Journal of the Japan Society of Colour Material
Online ISSN : 1883-2199
Print ISSN : 0010-180X
ISSN-L : 0010-180X
Volume 96, Issue 8
Displaying 1-5 of 5 articles from this issue
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  • Michihiro IIJIMA, Yuna SUGURE, Erika YOSHIHARA
    2023 Volume 96 Issue 8 Pages 255-260
    Published: August 20, 2023
    Released on J-STAGE: August 25, 2023
    JOURNAL RESTRICTED ACCESS

    Block polymers possessing both hydrophilic poly(ethylene glycol) (PEG) and multiple ionic poly(amino acid) (PAA) were synthesized precisely. A polymerizable reactive group was introduced quantitatively to the end of PAA by end-functionalization of the polymers. After preparation of micelle in water by using PEG-PAA block polymers, stable nanoparticles were prepared by polymerization of the polymerizable end group in the core of the micelle. Anionic poly(L-glutamic acid)(PGlu), cationic poly(L-lysine)(PLys) and hydrophobic poly(L-alanine)(PAla) were selected as the PAA segment. A new method to introduce ionicity while preventing gelation by deprotection of a hydrophobic protecting group in PAA after creating the target shape was studied. By deprotecting in an associated state, it is considered that ionicity can become stable by utilizing the dispersion stability of the PEG chain, and the introduction of multiple ionicity is possible. From the results of fluctuation of zeta potential and dispersibility, it was clarified that multiple ionicity can be introduced in the particle form. From these results, it is assumed that ionicity is easily introduced to the nanoparticle or material by using PEG-PAAs. These ionic polymers and nanoparticles are promising for medical and cosmetic fields, and as materials for inks or paints.

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  • Takeyoshi SUGAYA
    2023 Volume 96 Issue 8 Pages 275-279
    Published: August 20, 2023
    Released on J-STAGE: August 25, 2023
    JOURNAL RESTRICTED ACCESS

    The world’s highest-performance solar cells are Ⅲ-Ⅴ compound semiconductor multijunction solar cells. Due to their high performance, they are especially used for space applications. However, because of their high manufacturing cost, the market size of multijunction solar cells is small. In this paper, we describe the development of Ⅲ-Ⅴ compound multijunction solar cells, and the low-cost manufacturing technology that we are currently promoting. We discuss smart stack technology which can easily bond various semiconductors such as Si and Ⅲ-Ⅴ materials, and hydride vapor phase epitaxy which can grow Ⅲ-Ⅴ compound semiconductors at low cost.

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  • Takaya KUBO, Koichi TAMAKI, Hiroshi SEGAWA
    2023 Volume 96 Issue 8 Pages 280-285
    Published: August 20, 2023
    Released on J-STAGE: August 25, 2023
    JOURNAL RESTRICTED ACCESS

    Physical properties exhibited by quantum dots, such as quantum confinement effects, are interesting both as a subject of basic research and in terms of functional materials and device applications, and can be put to use in a wide range of application areas. Here, we describe the usefulness of colloidal quantum dots as optoelectronic device materials, as well as issues to be addressed for their functionalization. In addition, the current status and future prospects of solar cell applications utilizing the characteristics of colloidal quantum dots will be presented.

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