Dependence of photovoltaic properties in bulk heterojunction organic thin film solar cells utilizing soluble phthalocyanine derivative, 1,4,8,11,15,18,22,25-octahexylphthalocyanine (C6PcH
2) on acceptor materials have been investigated. As acceptor materials, we have adopted four fullerene derivatives, such as, 1-(3-methoxy-carbonyl)-propyl-1-1-phenyl-(6,6)C61 (PCBM), 1-[3-(methoxycarbonyl)propyl]-1-phenyl)-[6.6]C62 (bis[60]PCBM), Indene-C
60 Bisadduct (ICBA), and 1-(3-methoxycabonyl)-propyl-1-1-phenyl-(6,6)C
71 ([70]PCBM), which possess different LUMO or HOMO levels in their electric energy structures. The open circuit voltage (
Voc) of the solar cells was strongly dependent on the acceptor materials, and high
Voc of 0.97V could be achieved by using bis[60]PCBM. The photovoltaic properties, such as,
Voc, of the solar cells with the bulk heterojunction of C6PcH
2 and fullerene derivatives have been discussed by taking the energy diagrams of the materials used in this study into consideration.
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