Chemical separation of MgO from dolomite ore,CaMg(CO3)2,has been studied for the purpose of
utilization of mineral resources in a favored technique.The separation technique is based on the
following characteristics,
1) Remarkable difference in hydration tendency between CaO and MgO,calcined dolomite,results the
ready converstion to Ca(OH)2 when calcined dolomite is slaked in water.Assuming that MgO is
hydrated,the solubility in 100ml H2O is extremely low(9×10-4g)in comparison with Ca(OH)2(0.15g).
2) Addition of a strongly acidic cation exchange resin,H-form(H-R) to an aqueous suspension
containing calcined dolomite results in a selective ion exchange reaction with the dissolved
Ca(OH)2,which follows to consecutive dissolution of Ca(OH)2 powder to remain MgO powder.
3) MgO powder is separated effectively by sieving or by floatation method from the precipitated
mixture with Ca-R2.
4) Ca-R2,Ca-resin formed by the exchange reaction,is regenarated for reuse as H-R.
The study was done to confirm the foregoing facts using CaO and MgO chemicals with high purity (4N),followed by a laboratory demonstration to obtain MgO powder from dolomite.
Recently,special steel making is a newly developed blowing technique of BOF metaliurgy,utilizing low cost several ore.ln this case,it has caused with high temperature and strong agitation.
When evaluation of refractories was investigated by conventional corrosion test(rotary slag test and so on),it was difficult to select suitable refractories,particularly bath and bottom zone.ln this study,we made an attempt to test dynamic corrosion on the subject of MgO-C and MgO-CaO-C system refractories,using a high capacity indiuction furnace.
A simulation study has been performed to establish countermeasure against suitable corrosion to
MgO-C and MgO-CaO-C system refractories lining in BOF,and obtained satisfactory results both in
laboratory and actual mills.