The penetration of molten steel into porous refractory by applying extemal pressure to the steel was directly observed with the aid of a high temperat皿e X ray radiographic apparatus.The maximum penetration height increases linearly with increasing the extemal pressure.Data for the observed maximum penetration height was analyzed using a capillary model in which a labyrinth(or tortuosity)factorξwas introduced,that is,a modified capillary model. The minimum extemal pressure at which molten steel can penetrate into the refractory was in reasonable agreement with the value calculated with the capillary model.Discrepancies between the observed maximum values and those predicted with the modified capillary model were discussed from the view point of the labyrinth factor.
Using the crucible method,laboratory corrosion test on refractories was conducted in a simulated
incinerator ash under dry or wet 1.86%HCl gas at1000℃. In the case of corrosion test in ash,glass phase of Na-K-Si-O system was formed in the sample surface,and the mass of sample increased after corrosion test. Basic oxides included in the ash and the refractories changed the chloride under HCl gas.Since the formed chloride volatilized,the glass formation was inhibited.When there was no ash,the basic oxides included in grain boundary of the refractories volatilized,and embrittlement was generated.