Taikabutsu
Online ISSN : 2759-3835
Print ISSN : 0039-8993
Volume 42, Issue 12
Taikabutsu Vol.42 No.12 December 1990
Displaying 1-2 of 2 articles from this issue
  • Kusuhiro Mukai, Hiroshi Iwasaki, Tadataka Eguchi, Shoji Iizuka, Toguri ...
    1990Volume 42Issue 12 Pages 710-719
    Published: December 01, 1990
    Released on J-STAGE: July 01, 2024
    JOURNAL FREE ACCESS
     Kinematic immersion tests were conducted in order to substantiate quantitatively a mechanism for the Locat corrosion of immersion nozzles at the slag-metal interface.Based on the mechanism,then,experiments were designed to find out effective countermeasures for preventing the local corrosion.  The results obtained are summarized as follows:  For steels containing low carbon levels(e.g.,steel for continuous casting),the dissolution of oxides from the nozzle into the slag film is the rate controlling step of the local corrosion process.For metals containing high carbon content(e.g.,in the vicinity of carbon saturation),dlssolution of graphite from the nozzle into the metal is rate controlling.  If the nozzle:  1) has a high resistance to corrosion by liquid slags,and  2) is easily wetted by the slag.  then it will exhibit a good resistance to local corrosion at the slag-metal interface.  Zirconia-graphite nozzle containing ZrO2 which has a high resistance to corrosion by the slag much reduces its dissolution rate into the slag film.This mainly results in a remarkable lowering of the local corrosion rate.  Alumina-graphite nozzle containing BN and zlrconia-graphite nozzle containing SIC show good resistances to the local corrosion,which can be attributed to the fact that BN and SiC have good resistences to corrosion by the slag and are easily wetted by the slag.  The apparatus used for present lmmersion test is feasible for evaluating the local corrosion rate of zirconia-graphite nozzles for the condition of practical use.
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  • Satoshi Hayashi, Shigeyuki Takanaga, Hirokuni Takahashi, Akira Watanab ...
    1990Volume 42Issue 12 Pages 720-727
    Published: December 01, 1990
    Released on J-STAGE: July 01, 2024
    JOURNAL FREE ACCESS
     B2O3-MgO and B2O3-CaO compound oxides were added in MgO-C bricks and changes in wejght,mineral,strength and resistance to oxidation were investigated after heating at various temperatures ranging from 600℃ to 1400℃.  Adding only B2O3 compound,B2O3 reacted with C at temperature over 1200℃ and accordingly CO gas and boric vapors dlffused to outside.However,the addition of Al powder in MgO-C brick containing B2O3 compound controlled the diffusion and then the contribution to oxidation resistance and strength were developed.  Boric compounds function as both accelerator and inhibitor for oxidation depending on temperature and atmosphere.Therefore,when MgO-C brlck containing boric compound is practically used,it is necessary to use it in combination with metallc powder and to carefully study the proper amounts of additives.
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