Reaction model between magnesia and graphite in resin bonded magnesia-carbon bricks is proposed based on the measurement results of weight loss values and texture observation of two types of resin bonded magnesia-carbon bricks,named sample A and sample B,after heated under several conditions in 0.001atm.
Weight loss values calculated by using this reaction model agree with experiment values comparatively well.According to this reaction model,the dominant stage of the reaction in the early stage is the chemical reaction at the contacted borders between magnesia and graphite,and changes to be the diffusion of magnesium vapour and carbon mono-oxide produced by the reaction as time goes on. Each reaction rate coefficient kr of chemical reaction between magneisa and graphite is 1.5×10-2%/min・cm2 in the sample A and 2.3×10-2%min・cm2 in the sample B.
Each apparent activation energy Ea of this chemical reaction estimated by Arrhenius plot is 35kcal/mol in the sample A and 76kcal/mol in the sample B. lt is necessary to investigate more to clarify the causes of the difference between the sample A and the sample B.