Taikabutsu
Online ISSN : 2759-3835
Print ISSN : 0039-8993
Volume 39, Issue 12
Taikabutsu Vol.39 No.1 December 1987
Displaying 1-1 of 1 articles from this issue
  • Katsuhiro Tabata, Hideaki Nishio, Katsunori Ito
    1987Volume 39Issue 12 Pages 674-680
    Published: December 01, 1987
    Released on J-STAGE: July 01, 2024
    JOURNAL FREE ACCESS
      Reaction model between magnesia and graphite in resin bonded magnesia-carbon bricks is proposed based on the measurement results of weight loss values and texture observation of two types of resin bonded magnesia-carbon bricks,named sample A and sample B,after heated under several conditions in 0.001atm.   Weight loss values calculated by using this reaction model agree with experiment values comparatively well.According to this reaction model,the dominant stage of the reaction in the early stage is the chemical reaction at the contacted borders between magnesia and graphite,and changes to be the diffusion of magnesium vapour and carbon mono-oxide produced by the reaction as time goes on. Each reaction rate coefficient kr of chemical reaction between magneisa and graphite is 1.5×10-2%/min・cm2 in the sample A and 2.3×10-2%min・cm2 in the sample B. Each apparent activation energy Ea of this chemical reaction estimated by Arrhenius plot is 35kcal/mol in the sample A and 76kcal/mol in the sample B. lt is necessary to investigate more to clarify the causes of the difference between the sample A and the sample B.
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