A kinetic study has been investigated on the reaction between molten Cu-0.1%Si alloy and a Li
2O-SiO
2-Al
2O
3-FeO slag. The explored reaction was Si+2FeO=SiO
2+2Fe. The metal-slag melt was stirred by an alumina rod. The experimental temperature was 1250°C.
In one series of experiments, initial FeO contents of slag were varied from 5 to 15% at a constant rotational speed of the stirrer (200 rpm). The rate data could be represented apparently by linear relationship between log[%Si] and the time (t). Apparent mass-transfer coefficients of Si in metal,
k'
Si, were calculated. At initial FeO contents, (%FeO)0, below 9%, the reaction rate is controlled both by Si transport in the metal phase and Fe0 transport in the slag phase. At (%FeO)
0_??_9%, the reaction rate is controlled only by Si transport in the metal phase.
In another series of experiments, the stirring speed was varied as 70400 rpm at (%FeO)
0=9%. The mass-transfer coefficients,
k'
Si, were found to be proportional to the 0.5 power of rpm of the stirrer. This experimental finding can be ascribed to the fact that the reaction is of mass-transfer controlled.
The present reaction system has been established as a suitable model for the purpose of investigating the role of stirring in slag-metal reactions at high temperatures.
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