Rayon grade sulfite pulp (RP, α-cellulose 92%), acetate grade sulfite pulp (ACP, α-cellulose 96%) and purified linters (Linters, α-cellulose 99%) were oxidized by ClO
2 solution under the following condition : ClO
2 (as avail. cl.) add. : 0-40% basis B. D. pulp, temp : 70°C, initial PH : 3-11 (unbuffered), and average D P, copper number, carboxyl content, brightness, methoxyl content and also U. V. absorption spectrum of these treated pulps in ca. 80% H
3 PO
4 have been determined. The results areas follows :
1. With RP, the rate of oxidative degradation of cellulose by ClO
2 solution is very mild, with consequence of selective dissolution of residual lignin without affecting any influence upon functional groups (e. g. carboxyl, carbonyl groups). However, under the presence of extremely high amount of ClO
2 in the range of PH (initial) 7 or more, the degradation of cellulose also progressed gradually,
2. On the other hand, linters and ACP are very susceptible to the oxidation by C1O
2 and are apt to suffer from appreciable degradation, with consequence of decrease in a-cellulose, Cu-NH
3 viscosity, and increase in copper number and carboxyl content.
3. From these results it has been found that the noncellulosic material such as lignin and especially hemicellulose associated with cellulose has the protective action against the heterogeneous degradation of cellulose by ClO
2 solution. This phenomenon could be explained by preferential consumption of oxidizing agent by noncellulosic material. With this point, further discussion will be published in next report.
4. It has been found that the oxidized cellulose and hemicellulose have characteristic U.V. absorption spectrum near 290mμ.
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