Concerning pulp production from non-woody plants, we have been studying on the chemical pulping of rice and wheat straws since 1987. There are two reasons why this research project was planned. (a) More than 99% of pulp are produced from wood in Japan. Considering the increase of paper demands in future, it is doubtful whether or not we are able to obtain enough materials in future, and we may be obliged to use non-woody plants even in a small amount. For information, kenaf, non-woody plant is noticed recently as pulp materials. (b) China is well-known country to use non-woody plants like straw, reed, bamboo and so on as pulp materials. Soda cooking has been mainly adopted in the case of pulp making. However, the recovery of soda and the utilization of dissolved lignin in black liquor are not developed yet. This is due to a large quantity of ash which disturbs the post-treatment of black liquor. On the basis of two reasons above-mentioned, it is necessary for Japan to adjust the pulping process of non-woody plants seems to be appropriate at the present technical level. Moreover, the removal of ash from black liquor and the utilization of lignin are also indispensable to be solved.
This report describes the pulp analysis and the pulp sheet strength of rice and wheat straws by soda and alkaline sulfite cookings. Moreover, soda lignin was isolated from black liquor and sulfomethylated, and the dispersion property of sulfomethylated lignin was examined. The results are summarized as follows :
(1) Delignification of rice straw by soda cooking is more rapid than that of wheat straw. Corresponding with delignification, the brightness of the former is higher than that of the latter.
(2) The ash fraction is dissolved during soda cooking, although a few % of ash is still contained in soda pulp. However, the ash fraction during alkaline sulfite pulping is difficult to be dissolved, and 1617% of ash are contained in pulp. Such a high amount of ash may regulate the extensive application of alkaline sulfite pulp.
(3) Sheet strength of soda pulp is higher than that of alkaline sulfite pulp. However, these strength results represent only the preliminary work, because there is the difference of about 100 m
l CSF between soda and alkaline sulfite pulps.
(4) Standard dispersing number of sulfomethylated lignin is higher in rice straw than in wheat straw.
(5) Summarizing the previous (2) - (3) items, soda pulp is superior than alkaline sulfite pulp.
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