Handsheets from TMP, LUKP, NUKP, and NBKP were prepared for the examination of the distribution of extractive substances in pulp fibres by using ESCA. Whatman # 1 filter paper were also used as supplementary samples. Changes in C
1s peak and O
1s peak of above-described sheets by extraction with ethanol/benzene mixture, heat treatment and pulverizing treatment were observed. As the results, the following information was obtained :
(1) Extractives in pulp fibres are present at the surface of pulp fibres in higher concentration than the inside of fibre wall.
(2) When the above-mentioned sheets were subjected to heat treatment at 100°C for 48 hrs, extractives concentration at the surface of pulp fibres increased compared with those of untreated sheets. The increment were considered to be brought about by the extractives migrated from the inside of the fibre wall to the fibre surface.
(3) When the sample sheets were extracted in Soxleht apparatus with ethanol/benzene mixture, the extractives existing inside of the sheets were not removed completely. However, when the powder obtained by pulverizing the sheets were extracted, the extractives were found to be almost completely removed from the sample powder.
The above-mentioned information was mainly obtained from the excellent spatial resolution of ESCA, in which the photoelectron escape depth is about 10 nm from the sample surface.
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