In the 1 KP process at Nippon Paper Industries’Ishinomaki Mill which produce NBKP the usage of the domestic softwood species, which contain higher calcium (Ca) constituents than the conventional softwood, has increased in recent year. According to the increase usage of the domestic softwood, the adhesion and accumulation of the stains including the Ca scale for the digester and the other 1 KP process has been actualized with the in recent years. As a result, it has become difficult to maintain continuous operation (for six months) or led to decline in digestion efficiency, such as deterioration in steam consumption per unit.
Previously, the digester of 1 KP process have been cleaned with sulfamic acid at each shutdown (SD) to remove the stains including Ca scale. However, Cleaning with sulfamic acid had some issues and risks, which is the corrosion of the base material of the digester, highly workload with manual sulfamic acid dissolution etc.
To solve these issues and risks, we applied the chelating agents to the digester cleaning as an alternative to the conventional sulfamic acid cleaning. In this paper, the operational experience of the chelating agents cleaning for the digester is reported.
We tried the digester cleaning test with the chelating agents in the SD period, based on our past operational experience and the suggestion from Kurita Water Industries Ltd. As a result, Ca elution in the cleaning liquid from the digester was equivalent to that of the conventional sulfamic acid cleaning. Also, from the visual inspection of the top separator basket, the drastic removal of the stains including Ca scale was confirmed. Furthermore, there was little adhesion and accumulation of the stains including Ca scale to the A6 heater tube and the inline drainer basket. And the conventional high-pressure jet cleaning could be avoided.
The above results indicated that the application of the chelating agents to the digester cleaning is significantly effective, compared with the conventional sulfamic acid cleaning.
The chelating agents are expected to play a role on maintaining the stable operations, reducing the workloads, and ensuring the safety, and also contribute to the cost reductions and the improved profitability.
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