To establish chemical biorefinery for woody biomass, it is very important to convert lignin into value-added materials in addition to its use as an energy source. In this report, I would like to introduce its conversion to several valuable, functional materials on the basis of our recent research.
The first example is lignin-based carbon fibers (CF). In their production, spinning is a first process. There are proposed two methods, melt spinning and electro-spinning. The latter method for lignin was reported in the last decade. The second process is thermostabilization. The resultant lignin fibers prepared by both methods have high thermal mobility, such as glass transition and thermal flow. Thereby, the fiber morphology is changed by direct carbonization. To prevent morphological change, the thermostabilization process is very important. However, it is a tedious and time-consuming process. We developed a novel type of lignin fibers, which was easily converted into thermally stable fibers by the treatment with concentrated hydrochloric acid for 2 hs. The final product, CF, prepared from the lignin fibers had comparable tensile strength to lignin-based CF reported previously.
The other example for lignin-based functional materials is amphiphilic lignin derivatives, which are obtained by the reaction of isolated lignins or kraft black liquor with epoxylated polyethylene glycol. When these lignin derivatives were added to a saccharification medium using cellulase, the enzymatic saccharification efficiency was improved and residual activity of cellulase was maintained at a higher level. In addition, one type of the amphiphilic lignin derivative also had a superior ability for the cement dispersion to commercially available lignosulfonate that is well known as a cement dispersant.
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