To develop a new cooking system with highly concentrated polysulfide (PS) from the white liquor (WL) , effects of liquor to wood (L⁄W) ratio on hardwood pulp yield, kappa number and screened reject were investigated.
In industrialized technology available today, PS liquors are produced by air oxidation of kraft WL in the presence of a catalyst. Unfortunately, air oxidation promotes side reactions that limit the maximum concentration of PS in the produced liquor, which in turn limits the potential gain in pulp yield. PS and Na
2S concentrations are predominantly important for PS cooking. However, their concentrations in ordinary lab cooking using static autoclaves were often lower than mill continuous digesters because static lab cooking needs higher L⁄W to soak wood chips in autoclaves.
In this study rotating autoclaves were employed to realize lower L⁄W ratio cooking system relevant to the one in mill hardwood continuous digester.
The result shows yield gain of PS cooking became obvious at higher initial PS concentrations (1.7-4 g⁄l as S) in the condition with reduced screened rejects. Also, initial Na
2S concentrations on cooking have to be kept more than 6-9 g⁄l as Na
2O, to avoid increase of kappa numbers and screened rejects. PS have to be produced from Na
2S in the WL to keep Na
+ and S
2- balance in WL recovery cycle. To obtain the optimal effects of mill PS cooking, efficient and self sustained PS production methods with minimum Na
2S loss are desired.
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