An interstratified chlorite-montmorillonite mineral was found as an alteration mineral of tuff and tuffaceous sediments in the Neogene Tertiary “Green Tuff” near the Yamakata-machi, Kuji-Gun, Ibaragi Prefecture.
The <2μ fraction obtained by the sedimentation method contains about 3.2% quartz as an impurity. Chemical composition: SiO
2 37.82%; TiO
2 0.22%; Al
2O
3 14.72%; Fe
2O
3 6.47%; FeO 8.90%; MgO 14.36%; MnO 0.37%; CaO 1.81%; Na
2O 1.10%; K
2O 1.10%; H
2O (+) 7.10%; H
2O (-) 6.44%; total 100.41%. After subtracted 3.2% quartz from the chemical analysis, the structural formula was obtained as (Ca
0.357Na
0.391K
0.258) (Al
1.563Fe
+30.895Fe
+21.369Mg
3.938) (Si
6.371Al
1.629) O
20 (OH)
10. nH
2O.
X-ray examination of the natural material shows a reflection at about 31Å and its higher orders, but they make an irrational series. The montmorillonite-like layers expand with ethylene glycol and contract with heat treatment similar to montmorillonite. X-ray analysis revealed that the interstratification is produced by two component stacking of about 60% chlorite-like layers and about 40% montmorillonite-like layers. DTA and I. R. data are also described in this paper.
抄録全体を表示