The influence of various components on the stability of inosine 5'-monophosphate (IMP) in commercially available Umami seasoning (Dashinomoto) was investigated.
The thermal degradation of IMP in an extract of Dashinomoto was a first-order reaction at pH 4 and 7 and at 100°C. The rate constants were affected by pH and temperature, the halflife periods at 100°C being 8.1 (pH 4) and 15 hr (pH 7). The activation energy was about 1.5 × 10
5 J·mol
-1 at each pH index. These parameters were very similar to those of the thermal degradation of IMP in solution. However, the degradation of IMP in Dashinomoto at pH 9 did not proceed clearly according to the first-order reaction, suggesting that a chemical reaction possibly occurred between IMP and other components in Dashinomoto.
Dashinomoto powder was stored at 60°C under the influence of different water activities (
Aw). IMP was scarcely degraded at
Aw, 0, 0.2 and 0.5, but the degradation was remarkable at
Aw 0.8, suggesting that some interactions occurred between IMP and other components in Dashinomoto.
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