On cellulose and polyester films, the effect of addition of anionic poly (vinyl alcohol) (copolymer of vinyl acetate and sodium allyl sulfonate, designated as S-PVA) on the deposition of α-Fe
2O
3 particles was examined in suspended solution of α-Fe
2O
3. The results obtained were as follows.
(1) According to observation by scanning electron microscope, the particle size of α-Fe
2O
3 deposited on polyester fabrics varied with the amount of addition of S-PVA.
(2) The degree of deposition of α-Fe
2O
3 particles on the films decreased as the addition of S-PVA increased. This was also observed on the fabrics. However, at a small amount of addition (10
-4-10
-3 g/100 ml), the degree of deposition of α-Fe
2O
3 became extremely low in the case of films, but such extreme lowering was not observed in the case of fabrics.
(3) The coagulation of α-Fe
2O
3 particles was examined in S-PVA solutions. At concentrations between 10
-4-10
-3 g/100 ml, α-Fe
2O
3 particles remarkably coagulated. This concentration region was accordance with the concentration region in which the deposition of α-Fe
2O
3 on films extremely decreased.
(4) Thus, the extreme lowering in the deposition at a small amount of addition of S-PVA is supposed to be due to the mechanical disconnection which is caused by the coagulation of α-Fe
2O
3 particles. The coagulation may be caused by the formation of cross-linkage between S-PVA and α-Fe
2O
3 particles.
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