This paper reports the results of high-order harmonic generation (HHG) observed by changing the angleαbetween polarization directions in the pump and probe experiment using high-intensity femtosecond laser pulses. Theα-dependent HHG from an ensemble of aligned O
2 molecules was observed to be very similar to that from N
2, being contrary to what was expected from the higher occupied molecular orbital of a single O
2 molecule. It is shown that the characteristic angle dependence for O
2 is due to low degree of alignment of molecules that can be achieved in the pump-probe experiment. The experimental results for N
2 and O
2 are in good agreement with those calculated using the recently developed theory. This demonstrates the validity of the theory in describing the characteristic properties of HHG from aligned N
2 and O
2.
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