Optical emission spectroscopic studies were carried out on ablation plumes produced by laser ablation of graphite at 266nm and 1064nm in vacuum and in nitrogen gas atmosphere with or without a magnetic field of -0.1 T. In vacuum, in the presence of the magnetic field, the intensity distribution of C, C
+, and C
2+ emission lines were varied remarkably and some of the emission lines originated from relatively higher excited states became obscure. In addition, C
2 Swan band emission appeared particularly during 1064nm laser ablation. These changes in emission spectra are interpreted by promotion of ionization of C and C
+, formation of C
2, and deexcitation of electronically excited states, resulting from enhanced collisions between ablated species due to cyclotron motions under the magnetic field. In nitrogen gas atmosphere, enhanced N
2 emission (2nd positive system) was observed and explained by electron-impact excitation of N
2 molecules.
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