To obtain fundamental knowledge of pulsed laser welding phenomena, especially evaporation mechanism of different aluminum alloys, the authors investigated the structure and composition of evaporated particles of Al-Mg alloys in air and in the Ar atmosphere during pulsed laser welding. It was found that ultra-fine particles of 5 to 100 nm diameter in a globular or irregular shape were formed in laser-induced plume and the main structure was MgAl
2O
4. The composition of particles was different depending on the power density of a laser beam ; namely, under the low power density irradiation conditions, magnesium was predominant in the particles, while aluminum content increased with an increase in the power density. These results were attributed to evaporation phenomena of metals with different boiling points and latent heats of vaporization. On the other hand, under the assumption that the mixed gas of different atoms and the ionized species was an ideal one, the number density of laser-induced plasma species was obtained by Saha's equation. It was confirmed that the number density depends upon the plasma temperature and total pressures.
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