The temperature dependence of Hall coefficient of five superlattice alloys of Cu
3Pd, CuZn, Ni
3Cr, Au
3Cu and Ag
3Mg was measured to find the effect of order-disorder transformation upon it. At the transition temperature, the Hall coefficient of Cu
3Pd and Ag
3Mg showed a discontinuous change, while the change of Hall coefficient of other three alloys (CuZn, Ni
3Cr, Au
3Cu) are very small. Applying Muto’s theory, the qualitative discussion was made, and it was found that the general features of the temperature dependence of CuZn and Ni
3Cr are well understood by the theory. For Au
3Cu, the result of the experiment is explained by adopting the assumption of Schubert that each Au atom affords more than one electrons into the conduction band. The assumption also explains why the temperature dependence of Hall coefficient of Au
3Cu differs from that of Cu
3Au.
It remains unknown why Hall coefficient of Cu
3Pd takes strong minimum at transition temperature, while the abrupt increase of the Hall coefficient with the decreasing temperature below
Tc can be explained by the existence of a superzone in the ordered state. In addition, the result Ag
3Mg is contrary with that which Nicholas’s theory suggested.
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