The low field spin-lattice relaxation time
T1ρ of protons has been calculated in the rotating frame considering the effect of the quantum rotation of NH
4-ion. The weak collision case i.e. γ
HLτ
r<<1 has been treated, where
HL is the local dipolar field and τ
r the correlation time. The transition rates were calculated by using the phenomenological model of Clough and Punkkinen. It is shown that the temperature dependence of
T1ρ Shows a frequency independent minimum clearly when
Λ0>>γ
H1, which is in agreement with the experimental results, where
Λ0 is the tunneling frequency of NH
4-ion and H
1 the strength of rf field. Since the frequency independent minimum is easy to observe, the measurement of
T1ρ is useful to determine the tunueling frequency of NH
4-ion.
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