-
Hidetoshi Hiroyoshi, Kou Noguchi, Kazuaki Fukamichi, Yasuaki Nakagawa
1985 Volume 54 Issue 9 Pages
3554-3561
Published: September 15, 1985
Released on J-STAGE: June 01, 2007
JOURNAL
RESTRICTED ACCESS
Magnetization in high magnetic fields, thermomagnetization curves at low fields, hysteresis loops after field cooling and magnetic after-effect in the initial magnetization region have been investigated for Fe–Hf amorphous alloys containing 7.5–39 at.%Hf. The present results indicate the mictomagnetism or the Fe-rich alloys and the normal ferromagnetism of the alloys containing above 20 at.%Hf. The magnetic after-effect in the mictomagnetic alloys is explained on the basis of the thermal fluctuation theory using a domain wall pinning model.
View full abstract
-
Yoshichika \={O}nuki, Yohichi Machii, Yoshiaki Shimizu, Takemi Komatsu ...
1985 Volume 54 Issue 9 Pages
3562-3566
Published: September 15, 1985
Released on J-STAGE: June 01, 2007
JOURNAL
RESTRICTED ACCESS
We have measured the electrical resistivity, specific heat, magnetoresistance, magnetic susceptibility and magnetization of CeCu
2 single crystal in the temperature region of 1.4 K to room temperature. CeCu
2 is found to be a so-called dense Kondo substance with a large specific heat coefficient of 180 mJ/mole·K
2 around 10 K. The magnetic susceptibility and the negative magnetoresistance are extremely anisotropic, reflecting the orthorhombic crystal structure. The antiferromagnetic ordering is suggested below 3.0 K.
View full abstract
-
Kunitomo Hirai, Takeo Jo
1985 Volume 54 Issue 9 Pages
3567-3570
Published: September 15, 1985
Released on J-STAGE: June 01, 2007
JOURNAL
RESTRICTED ACCESS
By using a real space expansion approach to calculate the Green function of
d-electrons, the four-spin interaction is derived and the relative stability among various multiple spin density wave states is discussed for antiferromagnetic fcc transition metals with the first-kind ordering. The transition from a triple-
Q state to a single-
Q state is shown to occur with increasing or decreasing the number of
d-electrons from the nearly half-filled band region.
View full abstract
-
Isao Yamada, Koji Ubukoshi, Kinshiro Hirakawa
1985 Volume 54 Issue 9 Pages
3571-3576
Published: September 15, 1985
Released on J-STAGE: May 29, 2007
JOURNAL
RESTRICTED ACCESS
Recent experimental studies on NaTiO
2 and LiNiO
2 suggest that they might be rare compounds of 2D triangular lattice antiferromagnet with
S=1⁄2, the former being Heisenberg-like and the latter being Ising-like. We have studied ESR from 1.5 K to 300 K. In NaTiO
2 a broad ESR signal was observed at 300 K. A sharp ESR signal grows below ∼250 K and continues to increase the intensity toward 0 K. In LiNiO
2, we found clear dip in resonance width at 210 K corresponding to the para- to ferrimagnet-like transition but no change in resonance field on passing through it. Contrary to this, a remarkable divergence of the width was found at ∼19 K and a shift of resonance field starts below it, though no magnetic order has been detected by neutron scattering. Possible origin of these phenomena is discussed.
View full abstract
-
Masanori Arakawa, Hiroshi Ebisu, Hideo Takeuchi
1985 Volume 54 Issue 9 Pages
3577-3583
Published: September 15, 1985
Released on J-STAGE: June 01, 2007
JOURNAL
RESTRICTED ACCESS
EPR measurements on Gd
3+ centres in KCdF
3, RbCdF
3, RbCaF
3, CsCdF
3 and CsCaF
3 for crystals co-doped with Li
+ ions have been made in the cubic phase of host crystals. In all the crystals spectra for Gd
3+ centres associated with both cation vacancy (V
M) and Li
+ ion at the nearest divalent cation site have been observed. The observed parameters
b20 and
b44 in the spin Hamiltonian show various dependences on lattice constant in the series of fluorides with the same divalent (Cd
2+ or Ca
2+) or the same monovalent (Cs
+ or Rb
+) cation. The differences of the magnitude of
b20 and
b44 for Gd
3+–Li
+ centre from that for Gd
3+–V
M centre in the same host crystal are discussed.
View full abstract
-
Toshikazu Hirose, Masaru Kawaminami, Masanori Arakawa
1985 Volume 54 Issue 9 Pages
3584-3590
Published: September 15, 1985
Released on J-STAGE: June 01, 2007
JOURNAL
RESTRICTED ACCESS
The EPR spectra from V
4+ ions in WO
3 single crystal were studied in the temperature range from 300 K to 77 K by using a K-band spectrometer. At 77 K, the
g values and hf parameters
A of V
4+ ions were strong
c-axis anistropy, so that
gX=1.928,
gY=1.945,
gZ=1.815, (Eulerian angles; θ
g=3.9°, φ
g=45.8°, ψ
g=−0.2°), and
AX=−60.5 G,
AY=−55.0 G,
AZ=−190.4 G, (θ
A=4.4°, φ
A=43.6°, ψ
A=1.5°). The ground state of 3
d1 electron of V
4+ ion was determined to be |
xy〉 state by hf structure analysis. WO
3 is determined to be a ferroelectric material with the spontaneous polarization along the
c-axis connected to the condensed ferroelectric
Γ15z phonon modes of W
6+ ions in the monoclinic II phase at 77 K. At the relations of
gav vs
Aiso for V
4+ and VO
2+ ions in some host crystals, WO
3 is shown to be a remarkable material.
View full abstract
-
Youichi Ohno, Shun-ichi Nakai
1985 Volume 54 Issue 9 Pages
3591-3596
Published: September 15, 1985
Released on J-STAGE: May 29, 2007
JOURNAL
RESTRICTED ACCESS
The L
2,3 absorption spectra of the metal ions in layered 3d transition-metal thiophosphates MPS
3 (M=Mn, Fe, Ni) have been measured. Results are discussed by comparing with the spectra of other transition-metal compounds and with the theoretical calculation by Gupta and Sen. The spectra are interpreted in terms of the multiplet structure which results from the interaction between a 2p hole and 3d electrons of a localized metal ion. Since the p-d interaction is reduced by the delocalization of metal 3d orbitals, the multiplet structure becomes inconspicuous as covalency is increased. It is concluded that the near-edge structure of the metal L
2,3 absorption spectrum of an ionic 3d transition-metal compound exhibits the multiplet structure, while that of a covalent compound represents the projected density of states of the conduction band.
View full abstract
-
Eiji Kato, Teruo Komatsu, Yozo Kaifu
1985 Volume 54 Issue 9 Pages
3597-3604
Published: September 15, 1985
Released on J-STAGE: May 29, 2007
JOURNAL
RESTRICTED ACCESS
The elastic constants of BiI
3, and SbI
3 are determined by Brillouin scattering. It is found that the phase velocity of phonons propagating in an angle
Ψ to the
Z-axis is different from that propagating in an angle 180°-
Ψ for rhombohedral crystals. The elastic constants determined in units of 10
11 dyne/cm
2 are
C11=2.9,
C12=0.50,
C13=0.90, |
C14|=0.20, |
C25|=0,
C33=2.6 and
C44=0.70 at 83 K for BiI
3, and
C11=1.5,
C12=−0.50,
C13=0.40, |
C14|=0.10, |
C25|=0.25,
C33=0.93 and
C44=0.47 at room temperature for SbI
3. BiI
3 and SbI
3 show very low elastic anisotropy compared with other layered crystals. The phonon dispersion curves calculated by a one-dimensional chain model does not show a satisifactory agreement with the dispersion obtained from the present work.
View full abstract
-
Hiroyasu Nakata, Eizo Otsuka
1985 Volume 54 Issue 9 Pages
3605-3614
Published: September 15, 1985
Released on J-STAGE: June 01, 2007
JOURNAL
RESTRICTED ACCESS
Formation and decay kinetics of a bound exciton and a bound-double-exciton complex in zinc doped germanium are investigated by examining the dependence of photoluminescence intensity on excitation intensity and by time resolved photoluminescence measurement. Exciton capture cross section by a neutral acceptor is found to be 4.7×10
−16 cm
2 and the lifetime of the bound exciton 1.8 μs at 4.2 K. The stable closed hole shell structure of the bound-double-exciton complex is responsible for its long lifetime 2.1 μs and such a large capture cross section as 1.1×10
−14 cm
2 of exciton capture by a bound exciton. The electron capture process by an A
+ related complex is proposed for the formation of a bound exciton at low excitation. One can explain the broadness of the bound exciton line in terms of a displacement of Zn impurity from the center of the substitutional site in the exciton capture process.
View full abstract
-
Kazuo Saitoh
1985 Volume 54 Issue 9 Pages
3615-3621
Published: September 15, 1985
Released on J-STAGE: June 01, 2007
JOURNAL
RESTRICTED ACCESS
By tracing the ion density distribution in transverse phase space, planar channeling at small depth is investigated in detail. Damping of surface oscillations of nuclear encounter probability, as a consequence of motion of ions which do not reach equilibrium, is shown to be caused mainly by diffusion in transverse momentum. Depth evolution of phase space ion density is presented schematically and several quantities characterizing the equalization process are evaluated. The rate of approach to statistical equilibrium is obtained as a function of transverse energy. It is shown that well channeled ions which have oscillation amplitudes of about a quarter of the interplanar spacing are the hardest to reach equilibrium.
View full abstract
-
Eiji Hashimoto, Takeshi Shiraishi, Takao Kino
1985 Volume 54 Issue 9 Pages
3622-3627
Published: September 15, 1985
Released on J-STAGE: May 29, 2007
JOURNAL
RESTRICTED ACCESS
Doppler-broadened lineshapes of positron annihilation radiation in an aluminum single crystal after quenching have been measured as a function of temperature between 4.2 and 200 K. The peak parameter for positron annihilation in the trapped state at vacancies showed no significant temperature dependence below 80 K, while above 100 K, it showed an almost linear temperature dependence with a temperature coefficient about twice that found for positron annihilation in the free state. A low concentration of vacancies yielded a remarkable increase in the peak parameter as the temperature decreased below 80 K. The results showed a strong temperature dependence of the trapping rate of positrons at vacancies in the low temperature range.
View full abstract
-
Mihiro Yanagihara, Hideki Maezawa, Taizo Sasaki, Yasuo Iguchi
1985 Volume 54 Issue 9 Pages
3628-3631
Published: September 15, 1985
Released on J-STAGE: May 29, 2007
JOURNAL
RESTRICTED ACCESS
K
+L2,3 absorption spectra at room temperature have been measured for KF, KCl, KBr and KI. Tentative assignment for the spectra is made using the ligand field model.
View full abstract
-
Masatoshi Tanaka, Susumu Kurita, Masami Fujisawa, Setsuko Matsumoto
1985 Volume 54 Issue 9 Pages
3632-3637
Published: September 15, 1985
Released on J-STAGE: May 29, 2007
JOURNAL
RESTRICTED ACCESS
Reflectance spectra of single crystals of [Pt(en)
2][Pt(en)
2I
2](ClO
4)
4 and [Pt(en)
2][Pt(en)
2Cl
2](ClO
4)
4 have been measured in the vacuum ultraviolet region up to 25 eV, with synchrotron radiation. Halogen ion-dependent structures observed below 10 eV are ascribed to the transitions related to the valence bands originating from
p orbitals of halogens. The one-dimensional band structures for the two compounds are determined from these spectral structures and their polarization-dependences, with the aid of the tight-binding approximation.
View full abstract
-
Akito Kakizaki, Tatsuya Miya, Kenzo Naito, Isao Fukui, Hidenao Sugawar ...
1985 Volume 54 Issue 9 Pages
3638-3646
Published: September 15, 1985
Released on J-STAGE: May 29, 2007
JOURNAL
RESTRICTED ACCESS
Resonant photoemission in the bromides of Ni, Co, Fe and Mn has been observed for excitations near the 3
p thresholds of the metal ions. Resonance occurs all over the valence band spectra including satellites, and the resonance excitation spectra are similar to those observed in the chlorides. Some features in the main bands shift toward high-binding-energy side upon resonance. This shift gives rise to increase in the crystal field splitting on resonance for NiBr
2, FeBr
2 and MnBr
2, but decrease for CoBr
2; Racah parameters increase on resonance in all the bromides observed here.
View full abstract
-
Takashi Sakuma, Shoji Saitoh
1985 Volume 54 Issue 9 Pages
3647-3648
Published: September 15, 1985
Released on J-STAGE: May 29, 2007
JOURNAL
RESTRICTED ACCESS
-
Nobuyoshi Yamada, Tetuo Ohoyama, Hideki Miyajima, Yoshichika Otani
1985 Volume 54 Issue 9 Pages
3649-3650
Published: September 15, 1985
Released on J-STAGE: May 29, 2007
JOURNAL
RESTRICTED ACCESS
-
Kiyomitsu Suzuki
1985 Volume 54 Issue 9 Pages
3651
Published: September 15, 1985
Released on J-STAGE: June 01, 2007
JOURNAL
RESTRICTED ACCESS