The suitable concentration of acids and other conditions in ferrous-permanganate method after oxidation with persulfate for determination of Mn in ferromanganese were studied and the following results were obtained. (1) Acid concentration; Using 4 g of (NH
4)
2S
2O
8 in total volume 400 mL, Mn of 4∼28 mg was determined in the concentration range of 1.4∼2.6 N H
2SO
4, 0.6∼1.0 N mixed acid of H
2SO
4 and HNO
3 (3:1). (2) Boiling time; The time of boiling of the solution for oxidation of Mn by (NH
4)
2S
2O
8 using AgNO
3 was permitted till 5 min after decomposition of surplus persulfate. In above acid concentration, boiling for more than 6 min caused the decomposition of permanganic acid. (3) Influence of H
3PO
4; Using about 2 g of (NH
4)
2S
2O
8 in total volume of 200 mL, the amounts of H
3PO
4 added must be increased with the increase of Mn content. But when the total volume is made to 400 mL and 4 g of (NH
4)
2S
2O
8 are used, the addition of too much of H
3PO
4 would be useless. (4) The suitable procedure for the determination of Mn in ferromanganese was established and the analysis were carried out with several samples, and good results were obtained.
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