Firstly, sensory similarities of odor qualities between 22 aromatic compounds were factor-analyzed, and the relationships between factor loading matrix and physicochemical parameters were examined quantitatively by the multiple regression method. Parameters were selected such as the hydrophobic parameter π, electronic parameters Hammett's σ
m and σ
p, electronic parameter Swain-Lupton's F and R, and steric parameter MR (Molar Refraction).
Results.
(1) Aromatic compounds show a basic odor quality commonly, and it is modified by the physicochemical properties of the aromatic substituents.
(2) Odor hedonic is one of the standards for judging odor similarity.
(3) Odor qualities of monosubstituted benzenes consist of 2 main factors, the first correlates highly with saturated vapor pressure (it is referred to hydrophobic ability or solubility in lipids). While the second correlates highly with σ
m and σ
p, F and R, and MR (it is referred to electron donating and attracting ability, and the size of the substituents).
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