Kinetics of pyrolysis of a variety of materials was studied by means of a thermal balance, in order to have a knowledge of primary stage of 'carbonization.
The degasification rate of cellulose was related to the degree of polymerization, and also to the amount of carbonized residues.Owing to an addition of a minute amount of salts to cellulose, the temperature of maximum decomposition was lower and the degasification rate was accelerated remarkably.
In order to analyse the degasification curve obtained by a thermal balance, theore-tical equations of degasification rates were deduced from several assumptions, and were compared with experimental results.
It was discussed the relation between the structure of pyrolyzed materials and the rate and the activation energies of pyrolysis.
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