A corrosion test was carried out for copper substrates with a plated nickel undercoat and plated gold top surface, and the influence of the nickel-plating conditions on corrosion resistance was investigated by varying the kind of plating bath and the current density. The samples were characterized by X-ray photoelectron spectroscopy (XPS), electron-probe microanalysis (EPMA) and focused ion beam/scanning ion microscopy (FIB/SIM). From those results, it was confirmed that a Watt's bath was more effective for corrosion resistance than a sulfamic acid bath, and the crystallite size of the nickel plated with the Watt's bath was smaller than that with the sulfamic acid bath. From the EPMA results and the values of standard free energy of formation (ΔG
f°), the main corrosion products on the surface appeared to be nickel and copper compounds including the sulfate ion, which was not affected by the nickel-plating conditions.
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