In this country, under the temperate humid climate, it has been frequently observed that the medicinal injuries of field crops are caused by 2,4-D applied in soile as weed-killers. From the standpoint of soil chemistry, this injuries are probably governed by absorbed amount and the mobility of 2,4-D with water in soils. Some experiments were made by authors to resolve these problems, and the results obtained may be summarized as follows : 1. Absorbed amount of 2,4-D (Na-salt) by soils is various according to its applied amount; when applied 1 mg per 6g of soil, it amounts 3.2-16.2mg per 100 g of air dried soil, and applied 15 mg, it amounts 10-210 mg. Absorption rate of 2,4-D is higher in diluvial volcanic ash soils than in alluvial sandy loams. From the test of inhibiting effect on root growth of wheat seedlings, this absorption is found to be inversely proportional with the physiological activity of 2,4-D in soils. (Part 1) 2. 2,4-D absorbed by these soils except alluvial sandy loams is not so easily removed with water, a fairly amount of which seems to be fixed in insoluble form. This amount, designated as "a fixed amount", is accepted as of showing the mobility of 2,4-D in soils. When 2,4-D is applied 1 mg per 6 g of soil a fixed amount numbers 1.5-11.7 mg per 100 g of various soils. 3. Addition of Ca(OH)_2 to acid soils causes the decrease of the absorption rate and the fixation of 2,4-D. (Part 2) 4. Of the mechanisms of absorption and fixation of 2,4-D by soil, the following conclusions are got. a) Some positive correlations are found between 2,4-D and soils; absorption rate and fixation of the former and base exchange capacity and phosphorus absorption of the latter. (Table 3) b) Fixation of 2,4-D by soils decreases when the soils are treated with dil. NaOH, NaF and Na-citrate solutions. (Table 4) c) Absorbed and fixed amounts of 2,4-D by homoionic soils decrease in the following order : Al-soil, H-soil, original soil, and Ca-soil. The solubility of metal salts of 2,4-D in water increases in the following order : Al-salt, free-acid, Ca-salt and Na-salt. (Table 5 and 6) d) Soils, having a higher fixing capacity for 2,4-D, are all proved to be strongly allitic, in which aluminium soluble in water and dil. HCl or extracted in N-KCl being much. (Fig. 1 and Table 7) It may be, therefore, assumed that the absorption and fixation of 2,4-D by soils are mainly due to the combination with the active aluminium in soils.
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