Study on electropolishing of copper and copper alloys was begun by Dr. P. A. Jacquet in 1935, but it is not so popular as chemical polishing, that has been commercially used to obtain good luster to be applied as plating base.
Moreover, Dr. Jaquet's electropolishing solution containing phosphoric acid is quite effective for single phase copper or 7.3 brass, but not for the bronze containing tin alloy or two phase 6.4 brass.
Various kinds of electropolishing solution were tested for these alloys and polishing effect of phosphoric acid-chromic acid, and phospholic acid-chromic acid-sulfuric acid were found to be remarkable for various steels, aluminum alloys, etc. Characteristic curves of anode current density-bath voltage for the metals such as aluminum bronze, brass, tin bronze and nickelsilver of different heat treatment, were plotted to investigate and compare the polishing effect.
1) Aluminium bronze
Polishing of 6% Al bronze of solid solution of single phase is easy; but during polishing selective solution and pits so easily take place that cast material gives rise to casting segregation while solidifies. Polishing of 10% Al bronze of two phases of α+β is difficult, but that of quenched β phase of martensite needle structure is easy.
2) Brass
Polishing of 20%, 30% zinc brass of single phase is easy, but crystal structure occurs at low anode current density, pit appears at high anode current density, and dezincation will take place in a long run.
Polishing of 40% Zn brass of two phase of α+β is difficult but brilliant smooth surface is. obtained of quenched and annealed materials or low anode current density, while its dezincation is remarkable at high anode current density than in the case of 20%, and 30% Zn brass.
3) Tin bronze
Polishing of 4%, 8%, ahd 12% tin bronze of single phase is easy, but the more the content of tin increases, the more difficult becomes the polishing of low anode current density. Polishing of bronze containing over 15% tin of α+β phase, its β phase being of martensjte needle, is comparatively easy. Moreover, it is considered that the polishing effect is improved since the contained tin is dissolved by sulfuric acid in the polishing solution.
4) Nickel-silver
Polishing of nickel-silver of single phase structure is easy, and good polishing surface is obtained.
Electropolishing solution added with oxidizer (chromic acid) is superior for polishing to that without oxdizer, even in the two phases alloys. Moreover, the addition of sulfuric acid improves the electropolishing effect, preventing the formation of insoluble salt of tin in tin bronze.
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