Various methods of pretreatment of aluminum plates were investigated. As a result, the α-Al
2O
3 formed by anodic oxidation was better than the alumina by chemical treatment.
As reported in the first paper, the sample coated with the film by anodic oxidation in the mono or mixed dilute sodium perborate, sodium metasilicate, pottasium borate and lithium borate solution, followed by borosilicate system frit application were satisfactory. However, the effect of the mixed solutions on adhesivity was greater than that of the mono solution.
In the present study such treatments as the above were applied to lead enamel and phosphate enamel with the satisfactory result.
In the pretreatment of lead and phosphate frits, aluminum plates treated with mixed aqueous solution of sodium metasilicate (water glass), sodium perborate, lithium borate and sodium phosphate showed better adhesiveness than those treated with mono aqueous solution of these salt components.
The results may be summarized as follows:
1. In the bending test of lead system enamel, sodium metasilicate, sodium perborate and lithium borate were the most satisfactory compounds in the tests carried out in ternary mixture aqueous solution.
Lithium borate was most satisfactory of the three kinds of mono component aqueous solution.
In the thermal shock test, adhesion was not different in all mono component aqueous solutions.
2. In the bending test of phosphate system enamel, sodium phosphate was most satisfactory of the mono component aqueous solutions.
In the thermal shock test, adhension of phosphate enamel was not different from that of lead enamel in all mono component aqueous solutions. But ternary mixture solution gave satisfactory results.
Thus samples submitted to anode treatment in mixed solutions were superior in every respect to those treated in mono component solution.
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