BaTiO
3 rods were sprayed with a commercial rod spray gun and the physical, mechanical and electrical properties of the deposited film were investigated under various spraying conditions.
As the results of X-ray analysis of the film, the following 3 sorts of phases were determined according to the relation between the film structure and the distance from nozzle to substrate.
When the distance was up to 8cm, the degree of amorphous was lower with the decrease of the distance between the gun nozzle and substrate. When the distance was 8-10cm, a structural change rapidly occurred, whereby the structure of film was converted into tetragonal system at 10cm. When the distance was beyond 10cm, the degree of amorphous was gradually higher with the increase of the distance.
The tensile strength of the film was much greater than that of flame sprayed alumina.
The maximum dielectric constant attainable was 350, but higher values of dielectric constant will be obtained under some other spraying conditions.
The flame sprayed BaTiO
3 did not represent a transition point such as Curie point of 120°C as seen in the conventional BaTiO
3. The temperature coefficients of capacitance at the temperatures of -55-160°C ranged from 100 to 200ppm/°C, depending on the spraying conditions.
Peculiar characteristics of the film was observed when the film was subjected to aging tests at various temperatures. The rate of decrease of dielectric constant was lower when the aging temperature was higher.
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