It is important for the improvement of mechanical properties and corrosion resistance of the article to control the distribution of the plated metal on its surface. It is commonly known that alkaline bath always gives larger throwing power than acid bath. It is true in practice that distribution of metal produced by bright nickel bath is inferior to that by non-bright Watts' bath.
The authors studied on the control of throwing power by using a curved cathode in tank and investigated the effects given by brightening agents, surface active agents, bath composition, and operating conditions.
The following results were obtained:
(1) Addition of 1st class brightening agents hardly affect the throwing power. However, 2nd class brightening agents, except thiourea and gelatine, reduce the power and the reduction of the power is more remarkable when their amounts of addition are larger.
(2) Most of surface active agents improve throwing power, but they give lower values as seen in 2nd class brightening agents when their concentrations are excessively high.
(3) When sodium chloride, instead of nickel chloride, is added to Watts'bath, conductivity and throwing power of the bath are improved.
(4) In general, when current density is increased, throwing power is reduced. When air agitation is applied to the solution, throwing power is larger as compared with the case of no agitation.
抄録全体を表示