Among the successive stages of coalification, no definite demarcation is laid down betweeri the two adjoinirfg ones, being changed gradually each other in physical and chemical compositions.Nevertheless the composition of the changes sometimes, appear as an abrupt change in the porperties of coal, such as coking or non-coking.The cause of this fact is to be searched in the molecular state of coals of these successive series.
Coal consists of two dimensional layers of the carbon hexagonal network to which various kinds of side chains are attached.The dimension of the network is larger in the high rank coal than in the low.A difference by the rank of coal is also found among the chains, and -COOH, -OH and -CO groups are only rarely recognized in the fraction of humus.In the part consisting of sided chains, the molecular arrangement is conside-rablyrandom, and water and gas are adsorbed in free spaces among the molecules.As the dimension of the disordered part becomes larger, the rank of coal decreases.The amount of the disordered or non-crystal part in coal is naturally corresponding to its content of volatile matter in chemical analyses.On the other hand, the hexagonal network grown up to a considerable dimension, i.e.the crystal part is equivalent to the fraction of the fixed carbon, being stable on heating.
As polymers consist of various kinds of molecules, the bonds of which are different from each other in time of relaxation, an abrupt change in phase does not occur on heating, but transitional changes in phase forming broad transformation interval are commonly recognized.Coal is not the exception.The microbrownian movement becomes strong with the elevation of temperature until the thermal decomposition occurs.The softening of coal is obtained in a condition that is a little preceding the thermal decompo-sition of micromolecules, because the bonds are relaxed at such a high temperature.When the decomposition of micromolecules has occurred, cavities are made at the position of, the decomposed molecules and the other molecules flow along the cavities.The fluidity of coal is then recognized microscopically.
In the low rank coals provided with micromolecules of strongly polarized groups, bonds are not relaxed until the thermal decopmosition occurs.Softening and melting have not been found in such kind of coals.It is certain that anthracite, which is provided with none of the micromolecules unstable below 500°C, does not show such a thermal property as recognized in the bituminous coal.
Above all, the variation in composition of coals of various ranks is detected by the relative, amounts of the crystal and non-crystal parts and by the minor difference in chemical composition of the latter part.
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