Journal of the Fuel Society of Japan
Online ISSN : 2185-226X
Print ISSN : 0369-3775
ISSN-L : 0369-3775
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Volume 41, Issue 7
Displaying 1-14 of 14 articles from this issue
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  • [title in Japanese]
    [in Japanese]
    1962 Volume 41 Issue 7 Pages 566
    Published: July 20, 1962
    Released on J-STAGE: June 28, 2010
    DOIhttps://doi.org/10.3775/jie.41.566
    JOURNAL FREE ACCESS
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  • Metal Carbonyl
    Nobue Hagihara
    1962 Volume 41 Issue 7 Pages 567-583
    Published: July 20, 1962
    Released on J-STAGE: October 21, 2011
    DOIhttps://doi.org/10.3775/jie.41.567
    JOURNAL FREE ACCESS
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    The effective atomic number of metal in metal carbonyl is equal to that of rare gas, and metal-carbon bond is characterized by having doable bonding of σ-and π-bon-dings.This evidence shows the existence of stable metal carbonyl compounds with diffierent steric configuration by various kinds of metals.
    In the oxo reaction typical of various reactions in using the metallic carbonyl as catalyst, from the kinetic equation, products, isomerization and steric hindrance, a mechanism is postulated of the reaction that olefine is first coordinated to HCo (CO) 4 with Co2 (CO) 8 as catalyst. Reppe's alcohol synthesis can be well explained from this reaction mechanism.
    The diffence between metallic carbonyl and metallic solid catalyst is that the former soluble to organic solvent acts as homogenous catalyst and as such all metal atom has equal activity.
    Thus the metallic carbonyl gives selective and typical catalytic reaction.The cyclization reaction of acetylenes with the use of so-called Ziegler type catalyst such as AlR3-TiCl4, and AlR3-TiCl3 is very similar to that with metal carbonyl.
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  • Test Method of Fuel Additive
    Hiroshi Utsumi
    1962 Volume 41 Issue 7 Pages 584-589
    Published: July 20, 1962
    Released on J-STAGE: June 28, 2010
    DOIhttps://doi.org/10.3775/jie.41.584
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    On fuel additives, the test method has not been standardized, so users have been felt inconvenience.Lately, the test method of fuel additives was provided by the technical comittees of Japanese Ship Owners Association, so the author introduces the method as follows and offer for your reference.The method is provided on specific gravity, viscosity, flash point, sulfuric ash and degree of corrosion as general properties test, and as efficiency test, breaking efficiency for emulsion of oil and water, segregation for sludge, thermal stability and rust proof are provided.Beside this, the test method of efficiency for combustibility offer too as reference, And it is the purpose that those methods emphasized the main effect of additives, Hereafter, it is happiness that this-method will be corrected by relations and will contribute to makers and users.
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  • Diagram of Cetane Index
    Tsuyoshi Ogawa
    1962 Volume 41 Issue 7 Pages 590-592
    Published: July 20, 1962
    Released on J-STAGE: February 23, 2011
    DOIhttps://doi.org/10.3775/jie.41.590
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    A practical chart has been developed and tested for determining easily the cetane index by specific gravity (15/4°C) and 50% distillated temperature of high speed diesel fuel.There has been observed ±0.2 max error in the cetane index, between the formula of JIS K-2204 and this diagram.
    As a result of present investigations into several kind bases of light fuel oils, in addition, there has been shown ±2 max error in the cetane index when compared the cetane index with the cetane number measured.
    In the case of commercial test it may be carefully examined when the ignition quality is replaced by the cetane index.
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  • Studies on Naphthalene Manufacture (I)
    Takao Matsuda, Takeshi Takahashi, Tsunao Kakuzen, Hiroji Chiyajima
    1962 Volume 41 Issue 7 Pages 593-614
    Published: July 20, 1962
    Released on J-STAGE: June 28, 2010
    DOIhttps://doi.org/10.3775/jie.41.593
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    The conversion of methylnaphthalene and methyl-hydro-naphthalenes to Naphthalene was investigated.
    Methylnaphthalene can be converted to naphthalene with high yield over chromia alumina catalyst in hydrogen atmosphere, and methylhydronaphthalenes can be also converted to naphthalene using above catalyst, not requring the two stage method_ of dehydrogenation and dealkylation, but by the simple method of controlling the temperature gradient of one catalyst zone.
    The behabiour of benzene derivatives under the conditions of producing naphthalene was studied.
    Alkylbenzenes are also dealkylated and the long side chains are mainly hydrocracked.but partly cyclized to form naphthalene ring.
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  • Studies on the Oxo Reactions (II)
    The Oxo Reactions of C4-Olefines
    Kozo Kurokawa, Reiji Aizawa, Tozo Amemiya, Hazime Ino
    1962 Volume 41 Issue 7 Pages 615-623
    Published: July 20, 1962
    Released on J-STAGE: June 28, 2010
    DOIhttps://doi.org/10.3775/jie.41.615
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    1-Butene, 2-butene and iso-butene were hydro-formylated in the presences of cobalt naphthenate as catalyst and of Pd-zeolite as its promoter .Aldehydes thus obtained from I-butene and 2-butene were Iargely C5-normalaldehyde, while nearly 96% of the alde hyde from iso-butene was of iso-stucture.The Oxo reactions of 2-butene and iso- butene were much more accelerated by the co-presence of Pd-zeolite, compared with that of I-butene.
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  • [title in Japanese]
    [in Japanese]
    1962 Volume 41 Issue 7 Pages 624-628
    Published: July 20, 1962
    Released on J-STAGE: May 16, 2013
    DOIhttps://doi.org/10.3775/jie.41.624
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  • [title in Japanese]
    1962 Volume 41 Issue 7 Pages 629-630
    Published: July 20, 1962
    Released on J-STAGE: June 28, 2010
    DOIhttps://doi.org/10.3775/jie.41.629
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  • [title in Japanese]
    1962 Volume 41 Issue 7 Pages 629a-630
    Published: July 20, 1962
    Released on J-STAGE: February 09, 2012
    DOIhttps://doi.org/10.3775/jie.41.629a
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  • [title in Japanese]
    1962 Volume 41 Issue 7 Pages 631
    Published: July 20, 1962
    Released on J-STAGE: June 28, 2010
    DOIhttps://doi.org/10.3775/jie.41.631
    JOURNAL FREE ACCESS
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  • [title in Japanese]
    1962 Volume 41 Issue 7 Pages 631a-632
    Published: July 20, 1962
    Released on J-STAGE: June 28, 2010
    DOIhttps://doi.org/10.3775/jie.41.631a
    JOURNAL FREE ACCESS
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  • [title in Japanese]
    1962 Volume 41 Issue 7 Pages 633-635
    Published: July 20, 1962
    Released on J-STAGE: June 28, 2010
    DOIhttps://doi.org/10.3775/jie.41.633
    JOURNAL FREE ACCESS
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  • [title in Japanese]
    1962 Volume 41 Issue 7 Pages 635
    Published: July 20, 1962
    Released on J-STAGE: February 09, 2012
    DOIhttps://doi.org/10.3775/jie.41.635
    JOURNAL FREE ACCESS
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  • [title in Japanese]
    1962 Volume 41 Issue 7 Pages 635a-640
    Published: July 20, 1962
    Released on J-STAGE: February 09, 2012
    DOIhttps://doi.org/10.3775/jie.41.635a
    JOURNAL FREE ACCESS
    Download PDF (670K)
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