Three straight-run light lubricating oil fractions from Kuwait, Venezuela and California crudes were hydrotreated over NiCoMo-Al
2O
3 catalyst by the flow method for the purpose of studying the difference in reactivities of these three fractions and the relationship between the stabilities and the chemical composition of the oils. The reactivities of the fractions under hydrotreating were very different owing to their origins. Results were as follows;
(1) Under the mild conditions decrease in viscosity was proportional to the degree of desulfurization, but under severe conditions (above 80∼90% desulfrization) rapid decrease in viscosity by the cracking etc. was observed. In case of naphthenic oils containing much oxygen-compounds, considerable viscosity decrease was observed in the initial hydrotreating stage. It was supposed that these viscosity decrease was due to the hydrocracking of the oxygen-compounds.
(2)
CA% in ring analysis decreased according to the hydrodesulfurization. In case of Kuwait oils
CP% increased and
CN% did not change, on the contrary
CP% did not change and
CN% increased in California oils. And in Venezuelan oils both
CP and
CN% gradually increased.
(3) Oxidation stability of the hydrotreated oils had good relation with the total sulfur content of the oils. In the range of 0.1∼0.4wt% total sulfur, a maximum oxidation stability was obtained. Hydrotreated Kuwait oils and Venezuelan oils had these "Optimum sulfur range". California oils had inverse relationship, but after the undesirable nitrogen-compounds were eliminated, same "Optimum sulfur range" appeared in the same range.
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