化学工学
Print ISSN : 0375-9253
18 巻, 11 号
選択された号の論文の9件中1~9を表示しています
  • 平井 英二
    1954 年 18 巻 11 号 p. 528-531
    発行日: 1954/11/01
    公開日: 2009/07/09
    ジャーナル フリー
    Schwartz1) and Takasaki2) etc. measured the flow distribution, as soon as the liquid ran out of the packed bed. Their methods do not give the true distribution in a packed bed. Therefore the author investigated on the flow distribution of liquid in the tower packed with fine particles.
    In this experiment, 11 pairs of the platinum electrodes, 1mm in diameter and 1cm long, were placed in a packed bed as shown in Figure 1. And the flow distribution was measured by the electric current.
    The velocity profile is the complicated foam and not flate or parabolic, as shown in Figures 5 and 6.
    Near the wall, the velocity became large to a certain degree. And the minimum velocity occured approximately r/R 0.6-0.8.
  • 矢木 栄, 鞭 巖
    1954 年 18 巻 11 号 p. 532-538
    発行日: 1954/11/01
    公開日: 2009/07/09
    ジャーナル フリー
    Fluidized bed-type air preheater, as shown by Figure 1, is a heat exchanger with multiple fluidized beds applied to air preheating, and the volumes of this unit needed for the required weights of air to be preheated are considerably small compared with other types of preheaters.
    The sand (ie., heat carrier) charged in at the top of the tower is heated in the upper part of the tower by direct contact with waste gas and then is passed through a downspout to the lower part of tower, where the heat absorbed by the sand from the hot gas is given up to the air in the lower part of this unit having the conveying tube for cold sand. The subject of air preheating by means of the multiple beds of fluidized solids seems not to have been investigated so far. The purpose of this article is to report the results of the theoretical analyses which would be useful in clarifying the operation principle and predicting the performance of this unit.
    Basic equations were derived from the non-linear difference equations depending on the operating lines resulting from heat balances and the equations on the equilibrium relations assuming each plate to be under ideal state. Now, we employed the mean specific heat of fluid at constant pressure, over the ranges of temperatures considered, in hopes that this procedure might lead to the soluble linear forms. Analyses which were carried out differ in respect of the two basic equations, one when the effect of radiant-heat transmission between successive plates is taken into consideration, and the other when it is neglected.
    The unknown temperatures on the arbitrary i-th plate and the number of theoretical plates were given for each case (Equations (7) to (14) and Equations (21) to (31)), and the effects of radiation between successive plates and of the dimentionless ratio (K, K') upon the number of theoretical plates were shown. In order to compare with the analytical calculus, graphical solutions of this unit were illustrated in Figures 4 and 5, for practical operating conditions.
    Fundamental quantitative relationships represented in this paper are not backed by the experimental work, but this unit would offer an attractive subject of means of air preheating, from a commercial point of view.
  • 森川 清
    1954 年 18 巻 11 号 p. 539-544
    発行日: 1954/11/01
    公開日: 2009/07/09
    ジャーナル フリー
    最近豊富に蓄積されてきた気体あるいは蒸気の熱力学的の数値を用いて熱力学的数値の少い液相反応の平衡組成を計算する方法を述べる。気液両相が蒸発平衡に在り,また気相は理想気体,液相は理想溶液として取り扱えるものとすると,次式が導かれる。
    ここにKpは気相反応の分圧平衡恒数,KN(l)は液相反応の分子率平衡恒数,Kv.p.は蒸気圧平衡恒数と名づける新函数で,反応に与かる成分の蒸気圧を以て平衡恒数と同様に表わした比例項である。KN(l)は温度一定なれば一定値となる定数で,これより液相の化学平衡組成,平衡反応率,与反応系の全圧力も計算できる。結局気相反応の分圧平衡恒数Kpと各成分の蒸気圧の数値から液相反応の化学平衡の状態を計算することができることになる。
  • 亀井 三郎, 大石 純, 飯島 宏, 河村 姜男, 糸井 光夫
    1954 年 18 巻 11 号 p. 545-552
    発行日: 1954/11/01
    公開日: 2009/07/09
    ジャーナル フリー
    Many inquiries have been made, theoretically and experimentally, into the hold-up in a wetted wall tower without gas flow. Most of the results of experimental studies are said to satisfy the theoretical relation obtained by Nusselt who analysed the flow of liquid film, but in view of the precision of measurements in these studies it is to be doubted whether this conclusion holds true or not. It should be rather noted that Kirkbride and Friedman et al. recognized the generation of waves on the surface of liquid film where ReL>8.
    On the other hand no researches have been made about a tower with gas flow because the suitable method for measurements was lacking.
    The authors performed experiments with a new accurate method, the so-called balancing tower method. The towers used are shown in Table 1, and the liquids employed are water, soapless soap solution and millet-jelly solution. The results obtained are summarized as follows.
    In the case without gas flow,
    (i) The unsteady state parts of flow which existed at either end of the tower could be neglected when the length of the tower reached to about 250cm.
    (ii) The influence of diameter on the thickness of liquid film might be represented by the term (1-2h/d)1/3 regardless of the flow pattern.
    (iii) The plot of h(1-2h/d)1/3 vs. ReL showed three different aspects according to the values of ReL as shown in Figs. 4 and 5. Where ReL was small the data agreed with Nusselt's theoretical line N represented by eq. (2). This region might by considered to be a complete laminar flow region. As ReL grew larger, the plots deviated downwards from the line N. In this region the generation of waves was observed and seemed to have some influence on the flow pattern, and the effects of the surface tension and viscosity of liquid were very significant. The data were well correlated with eq. (9). This region could be named a pseudo-laminar flow region. Eqs. (10) or (11) gave the criterion whether the flow was laminar or pseudo-laminar. In the region of large value of ReL, the flow was fully turbulent and the influence of the surface tension of liquid diminished as in Fig. 6. Eq. (12) enabled one to predict the correlation in this region.
    In the case with concurrent gas flow the following results were obtained.
    (iv) When the liquid flows downwards in laminar film on a vertical surface, the ratio of the thickness of liquid film with countercurrent gas flow to that without gas flow, h/h0, is theoretically given by eq. (16). The data obtained were compared with this equation as shown in Figs. 8, 9 and 10. The plots scattered on account of the low precision of measurements but mostly deviated downwards from the theoretical lines. The deviation appeared to be caused by the waves which were visible on the liquid surface, and the degree of deviation decreased with decrease of the surface tension of liquid and with increase of the viscosity. The ratio h/h0 was expected to be smaller in turbulent flow than in laminar flow.
  • 佐藤 敬夫, 山崎 章
    1954 年 18 巻 11 号 p. 553-555
    発行日: 1954/11/01
    公開日: 2009/07/09
    ジャーナル フリー
    The traditional approximation, brings appreciable error with a slight raising of temperature or humidity of gas. Its numerical value in the adiabatic vaporization (cooling of gas) process is shown in Fig. 1. In an example of counter-current, constant-rate drying (adiabatic cooling) process, the required contact area has been given by A4, accompanying an error shown in Fig. 2, when ψ2=80%. Correct one is A1 of Eq. (6).
    The authors propose the new approximation, Eq. (2) or A2, instead of Eq. (4) or A4, by which the error becomes smaller by one order and to be within the safety range. Their comparison can be made by Fig. 2 & 4.
    This paper will have a relation to the discrussion about the accuracy of the Lewis' law, h/k'=CH. And the future precise investigation obout kG=f(G'), will attract the researchers' attention to the conversion erfor of kG to k'.
    In the case of taking kG as constant against instead of (ps-p), Eq. (3) will be better suited.
  • 主として大きさと形態
    水渡 英二
    1954 年 18 巻 11 号 p. 556-560
    発行日: 1954/11/01
    公開日: 2010/01/18
    ジャーナル フリー
  • 小林 三雄, 鮫島 寛, 藤田 富晴
    1954 年 18 巻 11 号 p. 561-563
    発行日: 1954/11/01
    公開日: 2009/07/09
    ジャーナル フリー
    ベンチュリースクラバーについてはすでに幾多の報文があり,その性能は一般に認められてきつつある。偶々筆者らは苦灰石粉砕現場の収塵を目的とし,最も簡単な型のこの種装置を製作試用し,実用上の2~3の点について検討を加えほぼ満足すべき結果をえているのでそれについて簡単に述べる。
  • 橋本 光一
    1954 年 18 巻 11 号 p. 564-565
    発行日: 1954/11/01
    公開日: 2009/07/09
    ジャーナル フリー
  • 稲積 彦二
    1954 年 18 巻 11 号 p. 566-567
    発行日: 1954/11/01
    公開日: 2009/07/09
    ジャーナル フリー
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