Three particular relative volatilities are generally required as minimum information to make a prediction of
x-y relation for the binary system at constant pressure.
The semiempirical method described in this paper permits the prediction of the three relative volatilitie sby the equation given as follows:
where α0 and α1 denote the limiting values of the relative volatility, at
x=0 and
x=1, respectively, and αm, the relative volatility at
x=0.5.
The predictions are based on the estimation of β
0 and β
1, the limiting value of the partial molal free energy, at
x=0 and
x=1, respectively, involving the field factor defined by Gilmont.
In addition, this method permits the estimation of the constant in the three-constant equation proposed for
x-y relation by Lu and the algebraic equation of this kind by Clark to cal culate the
x-y relation for the binary system at atmospheric pressure.
In our proposed method, the over-all average deviation in vapor composition bet ween predicted value and the experimental one is about 1.4 mole percent for sixteen systems.
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