真空
Online ISSN : 1880-9413
Print ISSN : 0559-8516
ISSN-L : 0559-8516
15 巻, 9 号
選択された号の論文の3件中1~3を表示しています
  • 中山 勝矢
    1972 年 15 巻 9 号 p. 316-323
    発行日: 1972/09/20
    公開日: 2010/01/28
    ジャーナル フリー
  • 伊佐 公男, 楠 勲, 小寺 熊三郎
    1972 年 15 巻 9 号 p. 324-331
    発行日: 1972/09/20
    公開日: 2009/09/29
    ジャーナル フリー
    Mean residence time of potassium atoms on polycrystalline tungsten filament surface has been studied. Beam pulse shorter than those of the measurements reported previously were used to improve time resolution. In order to measure the delay time of desorbed ions with an acceptable signal-to-noise ratio, sampling method was employed. From the dynamics of desorption of potassium atoms and ions, taking into consideration the shape of the gate function which has seldom been considered, the following formulas are obtained :
    G (p) /F (p) = (K+1/K) τ+p+ (1/β'+1) =θp+1/β :
    G (p) =α∫ 0 e-ptg (t) dt,
    F (p) =∫ 0 e-pt f (t) dt, where p is a parameter of Laplace transformation. G (t) and f (t) are gate function and intensity function of desorbed ions, respectively. The quantity a can be determined from the experiment. K is an equilibrium constant between the transient adatoms and adions :
    M (s) _??_ M+ (s) + e-
    β' is the degree of ionization and is considered to be constant under the same surface condition and temperature. A relation τ=βθ is introduced to make a comparison with the values in published papers. Scheer et al. estimated β by Saha-Langmuir equation using value of the work function of metals (Φ+) and the ionization potential (I) of alkali atoms, whereas β can be determined directly from experimental data. The temperature dependence of residence time of adions will be expressed by Frenkel equation of the form
    τ = τ0exp (l/kT).
    From this equation desorption energy (l) and the corresponding pre-exponential factor (τ0) are found to be 1.85 eV and 2.2×10-12 sec, respectively. These values are in good agreement with those of potassium ions on contaminated tungsten surface published by other authors.
  • 電導性高分子物質に関する研究 (第15報)
    広橋 亮, 飛鋪 靖
    1972 年 15 巻 9 号 p. 332-336
    発行日: 1972/09/20
    公開日: 2009/09/29
    ジャーナル フリー
    The effect of vacuum on the dark-and photo-conduction of polymers containing rhodanine or pyrimidine rings in the main chain was studied. The absorbed some oxygen and water on the surface of polymer were eliminated in high vacuum, so that the dark-current became very small and the photo-current under illumination of visible and ultra-violet rays became larger than that in an atmosphere.
    The surface dark- and photo-current of aromatic polymers containing π-electrons in the main chain were larger than that of aliphatic polymers containing σ-electrons.
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