The light scattering (LS) profile of a (polymer/liquid crystal) solution during solvent evaporation, exhibited a periodic structure, indicating that the phase separated structure was formed by spinodal decomposition. The faster the solvent was evaporated, the smaller the LC channel (domain) size in the composite film was. The electro-optical behavior of the composite film was strongly depended on the LC channel (domain) size in the composite film. The transmittance increased. and also, the rise and decay response times, decreased and increased, respectively, with an increase in size of LC channel (domain). Also, was concluded that an interfacial mixing induced by dielectric loss energy was one of an important origin for a hysteresis in a electro-optical switching. When a low-frequency sinusoidal electric field is applied to LC molecules, the anchoring strength on the polymeric wall might be evaluated on the basis of the distortion of high-order response wave (odd-order non-linear dielectric property).
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