Conducting polymers such as polypyrrole arc expected to utilize as electrochromic devices, because they change in their electrical conductivity and absorption of light, corresponding to doping and undoping of ions. However, it has been difficult to fit them for practical use, because these polymers are mechanically hard and brittle and they have only a short cycle-life when used repeatedly. To overcome these defects and to improve their practical performance, we developed a new method of conducting polymer films of good durability ; composite films of Polypyrrole (PPy) and the Poly vinyl-alcohol (PVA). By using this PPy/PVA composite, we developed a solid-state device of electrochromic display. The device showed color change (black & transparent yellow) more than 10^5 times under repeated and alternate application of DC voltages of ±0.9.
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