Proceedings of the Japan Academy, Series B
Online ISSN : 1349-2896
Print ISSN : 0386-2208
ISSN-L : 0386-2208
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Volume 84, Issue 3
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Review
  • Polyborylated reagents for modern organic synthesis
    Masaki SHIMIZU, Tamejiro HIYAMA
    2008 Volume 84 Issue 3 Pages 75-85
    Published: March 30, 2008
    Released on J-STAGE: March 12, 2008
    DOIhttps://doi.org/10.2183/pjab.84.75
    JOURNAL FREE ACCESS
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    Diverse kinds of gem- and vic-diborylated compounds are now readily available thanks to advances in gem-diborylation of lithium carbenoids as well as vic-diborylation of carbon–carbon multiple bonds with diboron compounds. These diborylated reagents lead to invention of polyborylated reagents and many novel and useful synthetic methods for supreme stereocontrol. This review summarizes preparative methods and synthetic reactions of di- and polyborylated reagents with the emphasis on multiple bond formation.

    (Communicated by Hitosi NOZAKI, M.J.A.)
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