In order to discover new radiation-sensitive nonsilver halide materials, the coloration based on the formation of Stenhouse salts was studied in the following three systems:(a) furfural -amine/HCl aq/methanol solution, (b) furfural-amine/polyhalogenide/PMMA matrix, (c) furfural-amine/PVC matrix.
Firstly, forty-five aromatic amines were surveyed to find out the amines suitable for the color precursors (reactant from furfural and amine) in the system (a). As a result, the five amines, which gave the precursors in good yields by the reaction with furfural, were selected:
m-nitroaniline,
N-methylaniline,
m-methyl-
N-methylaniline, aniline, and
o-methoxyaniline. Secondly, the coloration induced by electron beam bombardment was studied in the systems (b) and (c) containing the color pre-cursors (the reactants from these amines and furfural). Although the PMMA films containing the color precursors and polyhalogenides were sensitive to electron beam, they were not stable when standing under daylight at room temperature.
The PVC films containing the color precursors were very stable and colored to reddish yellow (λ
max 498-545 nm) by electron beam bombardment. The PVC film containing
N-methylaniline-furfural was the most sensitive and the increase in absorbance at 498 nm was 0.78 by electron beam bombardment of 60 kV-7.5×10
-7 C/cm
2. A good linear relationship existed between the degree of coloration and the amounts of electron beam bombardment in the range from 0 to 10
-6 C/cm
2.
抄録全体を表示