Boron compounds frequently used in organic synthesis are classified into three groups; i) reducing reagents, ii) hydroborating reagents, and iii) organoboranes. Synthesis, properties, and commercial availability of these boron compounds are described. Furthermore, typical applications to organic synthesis are briefly mentioned. The compounds listed are NaBH
4, NaBH
2S
3, NaBH
3CN, LiBH
3CN, Bu
4NBH
3CN, LiEt
3BH, Li and KsecBu
3BH, BH
3·THF, BH
3·SMe
2, BH
3·Amine, 9-BBN, Disiamylborane, Thexylborane, Dipinylborane, Catecolborane, BH
2Cl·SMe
2, BHCl
2·SMe
2, R
3B, 9-BBN-triflate, Aminohaloborane, 3-Pinanyl-9-BBN, and Boronic Esters.
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