Al-rich Al-Zn alloys were studied mainly by measurement of electrical resistivity. The results may be summarized as follows: (1) The resistivity ρ
0 immediately after quenching from various temperatures depends upon quenching temperatures
TQ, and is smallest when quenched from about 250°C. (2) Large values of ρ
0 which were obtained when
TQ was higher than 250°C may be due to G.P.zones formed during quenching. (3) Large values of ρ
0 which were obtained when
TQ was lower than 250°C may be due to clusters which exist at quenching temperature and are frozen in by quenching. (4) Maximum resistivity ρ
M during isothermal ageing depends upon the quenching temperatures. For instance, in the case of ageing of Al-4.4 at%Zn alloy at 40°C, ρ
M are constant when
TQ are in the range of 370°∼300°C. When
TQ is higher than 400°C, ρ
M increases as
TQ raises. When
TQ is lower than 270°C, ρ
M decreases. (5) It is considered that larger values of ρ
M are observed when the number of G.P.zones formed during quenching is larger than the number of G.P.zones which are usually formed at that ageing temperature. Smaller values of ρ
M which were observed when
TQ was lower than 270°C might be considered to show that the number of G.P.zones was decreased by clusters which were frozen in by quenching. (6) Metastable values of resistivity ρ
E which were obtained after resistivity maximum ρ
M depend upon both the number of G.P.zones formed during cooling and the concentration of vacancies. (7) Resistivity reaches a metastable value ρ
E′ in a short time when annealed at temperatures higher than the solvus temperature for G.P.zones and lower than the solvus temperature of the phase diagram. ρ
E′ depends upon annealing temperature
TA, and independent of
TQ. The values of ρ
E′ are on the extrapolated part of the ρ
0−
TQ curve. (8) The state corresponding to ρ
E′ might be a solid solution which contains clusters, and these clusters might be quite different from G.P.zones.
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