Finely and uniformly dispersed non-superconducting particles, Ag particles and Y211(Y
2BaCuO
5) particles in the single crystal Y123(YBa
2Cu
3O
7−x) matrix can improve the critical current density(
Jc) and mechanical properties. In this paper, the effect of solidification factors on the microstructure (size and distribution of Y211, Ag particle) was investigated. Mixed and pressed Y123+Y211(0, 10, 40 mol%)+Ag(10, 15 mass%)+Pt(0∼1.0 mass%) powders were melted and solidified unidirectionally under the thermal condition that promoted Y123 columnar crystal growth. Comparing with Ag-free YBCO, more Pt was required to refine Y211 particles in Ag added YBCO. Less than 0.8 mass%Pt addition was insufficient to refine Y211 particles. Though 1.0 mass%Pt addition completely refines Y211 particles, excess Pt formed Ba-Y-Cu-Pt-O compound. Liquid Ag droplets, formed by peritecto-monotectic reaction L
I+Y211→Y123+Ag(L
II), were pushed forward by the faceted freezing front and grew to capsule-like particles with a critical radius at a distance
L0 before they were trapped into Y123. In the 15 mass%Ag added sample, the mean radius,
r0(μm), the mean spacing, λ(μm), and the pushing distance,
L0(μm) of Ag particles dispersed in Y123 depended on the growth rate,
Ri(μm/s), and the relations were expressed by
r0=0.52·
Ri−1, λ=3.5·
Ri−1 and
L0=6.8·
Ri−1, respectively. The distribution of Ag particles in Y123 was quantitatively estimated based on the BCT (Body-Centered Tetragonal) array model.
View full abstract