Following the previous paper, the investigation on the flame retardant finish for cotton 35/polyester 65 (C/P) blended fabrics, higher ratio of polyester fiber, was continued for further improvement of the flame retardancy of finished fabrics.
The application of electron beam curing was attempted to the flame retardant finish of C/P blend and the results were compared with those observed for cotton 100% fabric as well as those obtained from the samples finished by heat curing.
The flame retardant which showed the most favorable result was vinyl phosphonate oligomer (Phoscon 76) out of those used for this study. C/P blend required 60% of Phoscon 76 while 40% was sufficient for cotton fabric to reach the LOI level above 28 even after 25 cycles of washing. As for the exposure dose, 50kGy gave durable flame retardancy to cotton 100% and C/P blend, but 100 kGy failed to give the flame retardancy to polyester 100% fabric.
The electron beam irradiation gave little effect on tensile strength of polyester 100% fabric, but considerable reduction was observed for cotton 100% fabric, consequently C/P blend showed some influence of such reduction. But, we have found that it is possible to inhibit the reduction of tensile strength by much weaker irradiation, 1/2 in intensity, on both sides of the fabric as well as by the aid of additives. The most adequate condition was to irradiate 40 kGy on both sides with the addition of polyphosphoric acid amide (Bonen H) as an additive.
Comparing the results observed for the flame retardant fabrics finished by electron beam curing with those by heat curing, C/P blend finished with vinyl phosphonate oligomer by electron beam curing clearly showed an improvement of flame retardancy. This fact well evidences the applicability of electron beam irradiation to the flame retardant finish of C/P blend as favorable as that to cotton 100% fabric.
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