Molecular energy transfers in a CO
2-N
2-He mixture are discussed. A supersonic flow of the shock-heated CO
2-N
2-He mixture is computed in a conventional conical nozzle, With the most reliable results of relaxation times in molecular energy transfers, using the two different methods; the RKG method and Time-dependent method. Theoretical results and shock-tunnel results of vibrational relaxations of CO
2 are compared.
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