No volatile compounds except methyl sulfide have been reported so far
Ulva pertusa K. The following results have been obtained by fractionating various acidic and neutral compounds contained in the steam-distillate of a large quantity of air dried Ulva.
1. After several preliminary trials, an appropriate method for the separation of volatile compounds in the steam-distillate has been devised and given in diagram 1.
2. The addition compound of methylsulfide with bromine showing the same melting point as Haas reported, has been obtained from fraction (2) which does not condense at thesteamdistillation. Atleast two carbonyl compounds have been isolated as their respective hydrazones from fraction (2).
3. The existence of several carbonyl compounds have also beenconfirmed in an ethereal portion (fraction 6) recovered from an ethereal extract of the steam-distillate.
4. From a soap fraction (13), obtained after saponifying the ethereal extract freed from free acid with dilute potassium hydroxide, have been isolated palmitic acid and an odorous unsaturated compound which loses its odour on the catalytic hydrogenation using palladium black.
5. Due to a small yield of free acids soluble in thesaturatedsolution of sodium bicarbonate (fraction 7), only an acid yielding p-bromphenacyl ester having m. p. 124-50°C. has been obtained so far.
6. The fraction of neutral compounds (14) gave on fractional distillation two fractions, one yielding 2, 4-dinitrophenyl hydrazone having m. p. 128°C. and the other, an a bromide showing a gradual decomposition between 174° and 190°C.
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