Seven unbleached sulfite pulps with different _??_ (1, 840-1, 070) were prepared from red pine (pinus densiflora), changing duration of hours at max. temp (140°C). These pulps were all purified in three stages, namely: chlorination, hot alkaline purification, and hypochlorite bleaching. The processing conditions to prepare the bleached pulp with same α-cellulose content and also same DP from each unbleached pulp, were investigated. The results were as follows:
1. The carboxyl content in unbleached sulfite pulp has decreased in proportion to the decrease in its _??_, but the copper No. remained about same irrespective of its _??_, varying within 1, 070-1, 840 _??_.
2. In hot alkaline purification, the decrease in pulp yield was about 2.5 time of the amount of the consumption of NaOH upon unbleached pulp, and the decrease in pulp yield due to increasing one present of α-cellulose content was approximately three percents upon the unbleached pulp. These results were very similar to that obtained by Meller, Leugering etc. in hot alkaline purification of beech and spruce. Also the direct proportionality of the decrease in copper No. to the decrease in pulp yield upon unbleached pulp was observed. The hot alkaline purified pulp with definite α-cellulose content, prepared from each unbleached pulp, has gradually lower copper No., 1% NaOH sol. and β-cellulose, and higher carboxyl content in increasing in _??_ of unbleached pulp.
3. In hypochlorite bleaching under higher pH like this experiment (initial pH=11.5 at 50°C), the copper No. and 1% NaOH sol. decreased and, on the other hand, carboxyl content increased in portion to the consumption of aval. Cl
2 upon hot refined pulp. The _??_ of each pulp dropped rapidly to about 600 with the consumption of aval. Cl
2 0.8_??_1.2% upon pulp, and these figures correspond to 0.09_??_0.14 O
2 per one anhydro-glucose unit. However, with further consumption of aval. Cl
2, the rate of drop of _??_ decreased gradually.
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