Sen'i Gakkaishi
Online ISSN : 1884-2259
Print ISSN : 0037-9875
Volume 21, Issue 8
Displaying 1-7 of 7 articles from this issue
  • PART IV. PREPARATION OF CELLULOSE PHOSPHATE AND ITS ELECTROLYTIC DISSOCIATION
    Kakuji Katsuura, Sadao Morishita, Yasuyuki Yamada, Norihiro Inagaki, K ...
    1965Volume 21Issue 8 Pages 399-404
    Published: August 10, 1965
    Released on J-STAGE: November 28, 2008
    JOURNAL FREE ACCESS
    Some preliminary experiments on the preparation of cellulose phosphate by the urea-phosphoric acid method and comparison of the electrolytic dissociation of cellulose phosphate with those of analogous polyelectrolytes led to the following conclusions:
    1) Autooxidation of cellulose in the condition of phosphorylation which leads to depolymerization can be avoided by conducting the phosphorylation in atmospheres of inert gases. The adsorption equibrium of urea and phosphoric acid to cellulose is established comparatively rapidly, but the difference between the ratio of urea to phosphoric acid adsorped to pulp fiber and the ratio in the aqueous mixture showes that urea is adsorbed by pulp fiber more strongly than by phosphoric acid.
    Pretreatment with various cellulose-swelling agents including some kinds of inorganic salts is useful to increase the amount of phosphorus combined with cellulose and phosphorus content is related to the degree of swelling. 2) The characteristics of water soluble cellulose phosphate in electrolytic dissociation and in the change of viscosity show a considerable resemblance to those of other polyelectrolytes which bear dibasic acid groups or two kinds of dissociating groups, but the neighboring groups in cellulose phosphate have the least effect on electrolytic dissociation. This indicates that the ionization strength of phosphoric acid group is least affected by the neighboring groups.
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  • PART I. DRAFT CURVE AND FALSE TWIST INSERTION
    Shinya Kurosaki, Fujio Konda
    1965Volume 21Issue 8 Pages 405-409
    Published: August 10, 1965
    Released on J-STAGE: November 28, 2008
    JOURNAL FREE ACCESS
    The effects of twister tube wihich seems very important for roller drafting of condensed slubbing are investigate.
    A tester (Fig.1) has been designed to draft condensed slubbings by roller drafting type under various conditions of draft ration, ratio, ratchm false twister speed and thread angle θ (angle between slubbing and center of twister tube), and to measure the tension generated.
    The reduction in weight percentage of the cendensed slubbing takes place within the drafting field, mainly in the proximity of the front roller inside the tube, and slightly at the back roller. (Fig.4_??_Fig.7) These two parts have less number of turns of false twist than in the other part. (Fig.8_??_Fig.9)
    The efficiency of false twister tube is high at slow speed, and low at high speed. (Fig.10)
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  • PART 3. ON THE MECHANISMS OF DETERIORATION OF THE ALLYLCELLULOSE AND ITS STABILIZING METHOD. PART 4. ON THE ALKALINE TREATMENT OF THE ALLYLCELLULOSE
    Saburo Yoshimura
    1965Volume 21Issue 8 Pages 410-424
    Published: August 10, 1965
    Released on J-STAGE: November 28, 2008
    JOURNAL FREE ACCESS
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  • (9) EFFECTS OF ORGANIC COMPOUNDS CALLED CARRIERS ON DYEING OF ACRYLIC FIBRES. (10) ABSORPTION OF CARRIER ON THE FIBRE AND EFFECTS ON THE PHYSICAL PROPERTIES. (11) THE MECHANISM OF CARRIER ACTION
    Akira Takaoka, Moloyuki Aki
    1965Volume 21Issue 8 Pages 425-442
    Published: August 10, 1965
    Released on J-STAGE: November 28, 2008
    JOURNAL FREE ACCESS
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  • (XV). EFFECTS OF SODIUM LAURYL SULFATE ON THE MIXTURE DYEING OF ACID DYES
    Masaru Mitsuishi, Gensaku Aida, Eiko Kosuge
    1965Volume 21Issue 8 Pages 443-447
    Published: August 10, 1965
    Released on J-STAGE: November 28, 2008
    JOURNAL FREE ACCESS
    In this paper, the effects of sodium lauryl sulfate on the mixture dyeing of nylon with monobasic dyes (C. I. Acid Orange 7, C. I. Acid Blue 43 and C. I. Acid Yellow 36) are considered.
    To examine the dyeing properties of three acid dyes used in this experiment for nylon, the affinities of dye acid for nylon in mixture dyeing are obtained. The affinities of Acid Orange 7, Acid Blue 43 and Acid Yellow 36 for nylon at 95°C are 14.9, 13.8 and 15.8 Kcal/mol respectively.
    The effects of sodium lauryl sulfate on the adsorption of each dye ion in mixture dyeing of Acid Orange and Acid Blue, and in mixture dyeing of Acid Yellow on Acid Blue are examined. The adsorption of each dye on nylon in mixture dyeing in presence of sodium lauryl sulfate is found to decrease as sodium laurryl sulfate in dye solution increases. This is considered to be due to the competition for dye sites on nylon betwwn lauryl sulfate ion and dye anions.
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  • (II) THE RELATION BETWEEN WHITENESS AND POLYMERIZATION DFGREE OF THE COTTON BLEACHED AT TEMPERATURES ABOVE 100°C
    Saburo Okajima, Kazuhiko Kurihara, Masahide Yazawa
    1965Volume 21Issue 8 Pages 448-451
    Published: August 10, 1965
    Released on J-STAGE: November 28, 2008
    JOURNAL FREE ACCESS
    High temperature pad-steam bleaching of cotton was experimented under the following conditions and the Hunter's whiteness W and DP of the bleached cotton were measured. The conditions: NaClO2 1_??_1.5%, pH 7_??_3.5, liquor ratio 1:1, temperature 110°_??_160°C, time 15 sec_??_20min. The results obtained are:
    (1) The rate of bleaching decreases remarkably as the pH of the NaClO2 solution increases, while the rate of depolymerization is influenced by the pH value not so severely as in the case of the rate of bleaching, Hence longer time is necessary for bleaching at higher pH, during which the depolymerization of the cotton proceeds remarkably. Consequently the bleaching must be made speedily by lowering the pH of the NaClO2 solution to 3.5_??_5, then the depolymerization is tolerable.
    (2) When a bleaching is made at 120°_??_110°C for 30_??_60 sec, using a 1.5% NaClO2 solution at pH 3.6, W and DP were 92 and 1100 respectively, DP of the unbleached cotton being 1270.
    It is conclude that a high temperature continuous pad-steam bleaching of cotton is possible under suitable conditons
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  • [in Japanese]
    1965Volume 21Issue 8 Pages 452-453
    Published: August 10, 1965
    Released on J-STAGE: November 28, 2008
    JOURNAL FREE ACCESS
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