窯業協會誌
Online ISSN : 1884-2127
Print ISSN : 0009-0255
ISSN-L : 0009-0255
65 巻, 739 号
選択された号の論文の10件中1~10を表示しています
  • 境野 照雄
    1957 年 65 巻 739 号 p. 171-175
    発行日: 1957/07/01
    公開日: 2010/04/30
    ジャーナル フリー
    Assuming that in an incorporation of insufficient mixing there exist groups of mean size z, consisting of the mixing ingredient, and that the group is a mixing unit in the incorporation, it has been indicated that the incorporation under consideration can be treated mathematically as a perfect mix. An equation to determine the mean size, z of the groups from a value of variance S2 of a imperfect mix has been derived and a degree of mixing, μ has also been defined through z as follows,
    μ=1/z=pq/S2R,
    where R is a sample size to be taken from the mix, and p and q are mixing ratios of ingredients. Furthermore, another equation to express a relation between variance S2 of the mix and mixing time, has also been derived through z, on an assumption that the value of z varies in the mixing procedure, in a way of unimolecular reaction,
    S22=(S022)exp(-ct)
    where, σ2 is the variance of the perfect mix, S02 an initial value of S2, and C a constant. The above equation has validity to some experimental data concerning mixing procedure of solid particles and morever may be applicable to other kind of mixing procedures such as homogenizing process in glass-melting.
  • ドロマイトクリンカーに関する研究 (第1報)
    田賀井 秀夫
    1957 年 65 巻 739 号 p. 175-179
    発行日: 1957/07/01
    公開日: 2010/04/30
    ジャーナル フリー
    As the burned dolomite has property to slake into powder when exposed to the atomospheric moisture during storage, several attempts to keep out this defect have been taken in industry and discussed scientifically. Previously, some experiments were reported by the author (at the meeting of Ceramic Association of Japan, October, 1950, abstract page 17; June, 1955, abstract of J. Cer. Ass. Japan, 63 [709] 296 (1955)) and a new opinion on this question was presented that the burned dolomite clinker might be protected against slaking by having their grain surfaces coated with some reaction products which formed at burning temperature between dolomite and its added substances.
    This paper deals with an electron-micrographic study to prove the author's view suggested formerly.
  • 長谷 川泰, 柳 正光, 川久保 正一郎
    1957 年 65 巻 739 号 p. 179-186
    発行日: 1957/07/01
    公開日: 2010/04/30
    ジャーナル フリー
    The colouration of silicate glasses by tellurium is obtained by melting in reducing conditions and their colours are various corresponding to the degree of reduction. They are yellowish green, pink, purple pink, and red purple and are shown in the C. I. E. chromaticity diagram. These colouration are deepend by reheating. The purple pink and red purple can be obtatied with the potassium containing glass. Sodium containing glass is only able to become orange pink to pink.
    The authors calculate the index of the reducing capacity for various reducing agents and then calculate the ratio of reducing agents to unit weight of tellurium for the reduction of tellurium to alkalitelluride in glass. Using these values the authors investigate the influence of glass composition on the effectiveness of various reducing agents. The necessary amount of reducing agent to produce red colouration is affected by the glass components and must be increased when glass contains such component as calcium oxide, zince oxide, barium oxide, lead oxide, especially boric oxide and arsenic oxide. With the exception of aluminium, many other reducing agents tested, i.e. zinc and tartaric salts, etc., are not effective for the multicomponent glasses.
    The authors allude to the result of L. Springer, Sprechsaal, 88, 192-193 (1955), which conclude that the silicate glasses are not coloured red by tellurium. From his data the authors assume that his failure to get red colouration with tellurium is due to the wrong selection of the sort and amount of reducing agent for multi-component glass.
    From the practical point of view the authors conclude that it is able to obtain the tellurium pink or red silicate glasses by selecting the glass composition and the reducing agent suitable for the formation of alkali telluride and polytelluride in glass melt.
  • 宗宮 重行, 山内 俊吉
    1957 年 65 巻 739 号 p. 186-190
    発行日: 1957/07/01
    公開日: 2010/04/30
    ジャーナル フリー
    アメリカ製ジルコニア質耐火煉瓦, ジルコニア質耐火断熱煉瓦の二, 三の性質についてしらべた. その結果の要旨は下記の通りであった.
    1) ジルコニアの変態に基づく異常膨脹収縮は, 加熱時に認められず, 冷却時に僅か認められる程度であり, X線粉末法による解析および偏光顕微鏡による観察によって等軸晶系ジルコニア約70%と単斜晶系ジルコニア約30%の混合物であることがわかった.
    2) ジルコニアはSiO2等の酸性物質に強く, MgO等の塩基性物質に弱いことが確かめられた.
    3) 緻密質と多孔質の800℃におけるジルコニア質耐火物の熱伝導率はそれぞれ0.00281, 0.00138 (cal. sec-1 cm-2-1 cm-1) で他の耐火物と比較して小さい.
    4) 酸化鉄と安定化ジルコニアとの反応はさらに研究を要するも, 酸化鉄とクロム鉄鉱との問のバースチング現象に類似している気孔の発生, 成長が認められた.
  • 作花 済夫
    1957 年 65 巻 739 号 p. 190-192
    発行日: 1957/07/01
    公開日: 2010/04/30
    ジャーナル フリー
    Glass fibers of 12 and 22μ in diameter were drawn from the glass melt, the temperature of which were kept at 1170°C during the fiber forming process. The composition of the glass used was as follows: SiO2 67, B2O3 12, BaO 2, K2O 9, Na2O 9.5, Al2O3 0.5% (in weight).
    The glass fibers were repeated at different temperatures between the room temperature and the softening temperature of the glass, and then were etched with hydrofluoric acid. The tensile strength of the reheated fibers was measured before and after the etching.
    It was found that, although the tensile strength of fibers decreased by reheating, it regained its original value when its thin surface layer was removed by hydrofluoric acid.
  • 毛利 定男
    1957 年 65 巻 739 号 p. C203-C209
    発行日: 1957/07/01
    公開日: 2010/04/30
    ジャーナル フリー
  • 宮崎 雄一郎
    1957 年 65 巻 739 号 p. C210-C214
    発行日: 1957/07/01
    公開日: 2010/04/30
    ジャーナル フリー
  • 水野 善郎
    1957 年 65 巻 739 号 p. C215-C218
    発行日: 1957/07/01
    公開日: 2010/04/30
    ジャーナル フリー
  • 佐々木 茂弌
    1957 年 65 巻 739 号 p. C219-C232
    発行日: 1957/07/01
    公開日: 2010/04/30
    ジャーナル フリー
  • 岩井 津一
    1957 年 65 巻 739 号 p. C233
    発行日: 1957/07/01
    公開日: 2010/04/30
    ジャーナル フリー
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